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« Happy LHC Day! | Main | Another Week of GW News, September 14, 2008 »

Greenhouse theory violates the laws of thermodynamics

Category: sceptic guide
Posted on: September 11, 2008 9:14 AM, by coby

This is just one of dozens of responses to common climate change denial arguments, which can all be found at How to Talk to a Climate Sceptic.


Objection:

The so called "Greenhouse Effect" which is the underpinning of the entire theory of anthropogenic global warming claims that greenhouse gases in the upper atmosphere absorb outgoing long wave radiation from the surface and reradiate it back, thereby warming the climate. But the upper atmosphere is colder than the lower atmosphere and the surface and the second law of thermodynamics clearly requires that heat flow from warmer areas of a system to colder ones, the opposite direction that greenhouse theory requires. The cooler atmosphere can not radiate energy to the warmer surface. The greenhouse effect is a myth because it violates the second law of thermodynamics!

Answer:

No argument with the second law of thermodynamics here, that one seems to be on pretty solid ground! But the train of logic above has a subtle problem in its over statement of the constraints this law places on energy flow. Given a warmer and a cooler body exchanging energy either through convection or through radiation, the fact is, energy is constantly being exchanged in both directions. The second law of thermodynamics does not apply to individual molecules, it applies to the net flow of energy in the entire system. How could it be otherwise?

When an excited molecule of CO2 releases a photon, it does not somehow "know" which way to send it. It can not aim it towards a cooler body. It is simply released in a random direction. In the case of CO2 in the atmosphere, having absorbed some of the energy radiating towards space from the surface of the earth, this random choice of direction means that, roughly speaking, half of that energy is sent back. An individual molecule is not influenced at all by the temperature of the earth's surface.

Where the second law does apply is in the net flow of heat, and this happens because a warmer body will send out more energy overall than it is receiving from the cooler one. Lots of energy going back and foth, but on balance more is leaving the warmer body.

The IPCC has provided this nice graphic of what is going on. They have also used the analogies of a blanket and a garden greenhouse in their FAQ sections.

(click for a slightly larger image. Courtesy of the IPCC)

In the case of the simplified earth-atmosphere system, the Earth's surface warms from the sun's incoming shortwave radiation. As it is now a warm body floating in cold space, Earth radiates long wave energy back out at a rate that is dependent on its temperature. If that were the whole story, the earth would have balanced its incoming shortwave with its outgoing long wave radiation at an average surface temperature of roughly -18oC and it would be a rather inhospitable place. As it is, the content of greenhouse gases in its atmosphere absorb some of that outgoing long wave radiation and send it back down where we all live. The earth must balance this by warming enough so that it can radiate this additional energy back out again. The totality of this natural effect is around 33oC, bringing our average surface temperature to a comfortable +15oC.

So, it is not really like a blanket, which inhibits convection in both directions, or like an actual greenhouse, which lets in the sunlight and then also inhibits convection, but both are reasonable analogies as far as they go. The scientists in the IPCC know this, they are only using these analogies to help laypeople understand the very general principals. If you hear someone attacking climate science by attacking these analogies, they are attacking a strawman.

As we have added to the greenhouse efect, the planet's surface must now warm until it reaches a new equillibrium temperature high enough to radiate out as much again as it is now receiving.

This is all very well established and long standing physics. No basic ignored mysteries, no violations of fundamental laws, just great explanations of naturally observed phenomena all over the solar system and beyond.


This is just one of dozens of responses to common climate change denial arguments, which can all be found at How to Talk to a Climate Sceptic.


"Greenhouse theory violates the laws of thermodynamics" is also posted on the Grist website, where additional comments can be found, though the author, Coby Beck, does not monitor or respond there.

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Comments

1

Well the holes in the argument come from absorbtion of the the "long wave radiation". That is .7 to 100 micro meters. Fine, but CO2 only has a few bands where it will absorb the radiation, 2.7 4.3 and 15 um. We know this from IR spectroscopy. Looking at the molecules as a point source, like you have done means that on average half the energy is radiated back to space. As you say you can't decide which way it is going to emit. Secondly, the band widths that are absorbed are less than 4% of the black body radiation emitted back into space. So with a doubling of CO2, in increase of .0385% in the atmosphere times the 4% of black body radiation that is absorbed, would mean an increase at most of .00154%. So even based on your level of understanding of radiative capture you would see increase in temperature of that would take 20 C or 293.15 K to about 293.154 degrees K. Then you would have to divide that by half since only half the world is getting sun at one time so you would see a significant drop in black body radiation during the night time(It doesn't go to zero). Not to mention the fact that as the temperature increased, the absorbtion would go down as the gases in our atmosphere expanded. Anyway, its a stupid theory that doesn't hold water under scrutiny.

Posted by: Shane | September 12, 2008 8:10 AM

2

Given the Greenhouse Effect the value of outgoing solar radiation, 103w per sqr(m) should be decreasing over time. Have we ever put a sensor on the Moon to measure the Earth to see if it is "cooling" in proportion to the amount of retained infrared that never makes it to outer space?

Posted by: John Bailo | September 13, 2008 11:18 AM

3

It's weird that the deniers don't get that a small shift in a dynamic system at equilibrium can lead to a larger shift in the overall system. A very tiny amount of heating over a large area can result in things like methane emissions from soils and decarbonization of soils that lead to more CO2 releases that lead to more heating.

Of course the extra CO2 in the atmosphere isn't that small of a shift but rather the release of gigatons of carbon stored over millenia of geologic time in an eyeblink. Remineralizing that carbon is a massive task that we barely understand the beginnings of.

Posted by: Pangolin | September 14, 2008 3:06 AM

4

John Balio:

We tried (actually at L1, which is where you would want this instead of the moon), but it was basically mothballed by the Bush administration. The satellite (DSCOVR) sits, completed, in a box somewhere costing taxpayers a million dollars a year. It's not the lack of launch options -- other countries (the Ukraine, IIRC) have offered to launch it for free and been rejected.

Ask yourself this: Given the existence of a multimillion-dollar probe that can, definitively, answer questions pertaining to the Earth's energy balance (i.e. directly measuring the bottom line of all climate change arguments, from a physics perspective), what possible reason would there be for such opposition from the White House?

(Hint: Uncertainty is the inactivist's best friend. Go and read Doubt Is Their Product.)

Posted by: Brian D | September 14, 2008 6:19 PM

5

(delurk)
and 1e6 has nuttin to do wiv it. honest.
I don't need no prize b/c I'm a scientist on the well paid IPCC band wagon.

Anyhow, ya know good old Chris de Freitas (of Soon and Baliunas fame) had a press release along these lines a while back. (Issued under banner of the sceptic group for which he is a "scientific advisor" - I ain't telling you who as they don't need the hits).

He took issue with a govt website for school children describing a experiment with a glass jar an a thermometer to demonstrate a greenhouse effect.

He said: "The surface of the Earth is warmer than it would be in the absence of an atmosphere because it receives radiant energy from two sources the sun and the atmosphere. To claim or demonstrate that the atmosphere behaves as a greenhouse is grossly misleading."

I told him it was grossly misleading for him to imply that just b/c the atm does not work like an actual factual greenhouse then therefore GHG were not the responsible for retaining heat.

Next day he took all his articles of the sceptic website. Coincidence?

Not to say he has been silent since then. Far from it. A few weeks ago gave a seminar to the Dept of Statistics at my University about lies and deceit in an article he co-wrote earlier this year that appeared in a mass circulation magazine.

de Freitas also said in the same press release that: "The website also informs are children that the greenhouse gases in our atmosphere as mainly carbon dioxide, methane and nitrous oxide, when in fact the main greenhouse gas responsible for controlling climate is water vapour."

and him a doktor and all. shame.
nuff said.

Posted by: Doug Mackie | September 15, 2008 11:11 PM

7

The main site pushing this bunk seems to be http://nov55.com/ntyg.html

Gary Novak says:

CO2 Absorption Spectrum
There is no Valid Mechanism for CO2 Creating Global Warming

Proof one: Laboratory measurements show that carbon dioxide absorbs to extinction at its main peak in 10 meters under atmospheric conditions.* This means there is no radiation left at those frequencies after 10 meters.

Posted by: notes | November 13, 2008 6:11 PM

8

That "Proof one" stuff should have been inside the blockquote. Sorry.

Posted by: notes | November 13, 2008 6:21 PM

9

I note that no one has addressed Shane's comment, other than "notes", who can only say, "... carbon dioxide absorbs to extinction at its main peak ...". The key phrase there, notes, is "at its main peak". Carbon dioxide absorbs Infrared Radiation (IR) only at two very narrow ranges of wavelength, one between 2.5 and 3 microns, and another between 4 and 5 microns. I don't know how much of the total IR radiation is emitted in those ranges, but, even if it's a uniform probability distribution, it couldn't possibly be more than 10-15% of all IR. If it's a (more likely) normal probability distribution, then the percent of all IR that falls in those two ranges would be more like 5%.

Now, I'll take your word for it, notes, that WITHIN THOSE RANGES, CO2 absorbs 100% of IR radiation. But that leaves 85-95% of IR that IS NOT ABSORBED AT ALL by CO2. So, let's focus on just that 5-15% of IR that IS absorbed by CO2. Even within the range of wavelengths at which CO2 absorbs IR, it has to COMPETE with Water Vapor for that IR. There is only so much IR being emitted in those ranges. What that means is that, as CO2 levels increase, the marginal aborption of IR per ton of CO2 decreases, and, at some point, additional CO2 will not increase IR absorption AT ALL. No one seems to know exactly what that point is. Some skeptics say that, at around 400 ppm CO2, we are very near that point now. Others say we have surpassed it. And a few say we surpassed it long before the beginning of the industrial revolution. Don't ask me what the alarmists say, because they don't talk about this. To hear the alarmists talk, you would think that CO2 absorbs ALL wavelengths of IR.

Posted by: Trevor | January 26, 2009 12:53 PM

10

Trevor,

In regards to C02 saturation, I have searched through all AGW propaganda and have found nothing that discusses this very issue. Maybe Coby is aware of something that he can provide a link to?

I suspect the models do not factor in this which is why they are so wrong. It would also point to why C02 continues to rise whilst temps are going down (regardless of what some say).

Just out of interest according to the IPCC pre industrial levels of C02 was 280ppm and current levels are 385ppm, however market gardeners that use green houses use C02 levels in the order of ten times this amount to promote growth, they also found that if C02 levels fall to below 250ppm plant growth declines appreciably and 150ppm PLANT GROWTH WILL STOP. Based on this we know through scientific fact that the current levels are just above the threshold to sustain all forms of life on the planet.

Yet at the same time based on IPCC guesswork C02 levels are high enough to destroy all life on the planet. Does this make sense to anyone?, of course not.

Note: I can use the green house analogy because AGW proponents used it first.

So no the AGW theory does not violate the law of thermodynamics, however the AGW theoretical results are grossly overstated.

Posted by: Crakar14 | January 26, 2009 7:32 PM

11

Crakar,

Read this article here, it should not have been hard for you to find. Of course climate scientists are very aware of these absorbtion issues, even if media outlets are not.

When you say things like "based on IPCC guesswork C02 levels are high enough to destroy all life on the planet" it is pretty hard to take you seriously.

Posted by: coby | January 26, 2009 8:03 PM

12

Thanks for the link, interesting reading, however i was after a link which explains how the IPCC achieved thier predictions, what if any experiments were carried out and what were the results etc as opposed to a GCM.

I regards to your link i am not sure the author quite understands what he is talking about, maybe he is getting confused with the term "saturation". When a C02 molecule becomes "saturated" it does not pull out of the race so another one can become "saturated". C02 can only absorb so much IR once this point is reached the addition of extra C02 has very little effect.

Sorry if i offended in the term quesswork maybe i over stated it for effect but after 8 years into a 100 year projection of C02 levels the IPCC have already got it wrong with no reduction in GHG's as yet. Just another case of model predictions proven wrong i guess.

So yes i still find it difficult to accept that below 250ppm plant growth is visably reduced but 385ppm threatens human life (Hansen and we only have 4 years etc).

Cheers

Posted by: Crakar14 | January 26, 2009 9:36 PM

13

Hey, Coby, thanks for the link.

No, I REALLY mean THANK YOU. You see, before this discussion, I was assuming that ALL of the IR in the absorption bands of CO2 was staying in the atmosphere. So, if Shane is right about those bands covering 4% of all IR, then that meant 4% of the IR was held in the atmosphere by CO2. But I wasn't considering that half of the IR re-emitted by CO2 was going UP instead of down, and some of that would eventually reach space. So, now I know that the upper limit of how much warming CO2 can cause is actually somewhat less than would be caused by the 4%. How much less depends on the concentration of CO2 in the atmosphere.

Using the link you provided, and a simplified model (5 discreet levels) of the atmosphere, I have worked out how all this bouncing around between layers works, and the results under different scenarios. At the (for lack of a better word) "saturation point" of CO2 (the point where it absorbs 100% of all IR at surface pressure), about 76.8% of the IR (within the CO2 absorbtion bands) ends up back on the surface, causing warming, while about 23.2% floats off into space. If you double the CO2 concentration, 89.3% comes back to the surface, and 10.7% goes into space. If you double it again, 93.0% comes back to the surface and 7.0% goes into space. If you double it once more (up to 8 times the original level of CO2), you get 94.1% coming back to the surface and 5.9% going into space. And it turns out, at least at the level of precision I was using, this is the maximum amount of IR going back to the surface (and minimum amount of IR going into space). I even tried using a factor of 1 million times the saturation point (to achieve this, the "saturation point" would have to be 1 ppm, and the entire atmosphere would have to be CO2), and I still can't get more than 94.1% of IR coming back to Earth.

(At this point, I'll concede the limitation of my model, being discreet. If I had the math skills to apply differential equations to this model, and allow for an infinite number of layers, I could probably get a more precise estimate of how much IR goes where. But I think it's safe to say that 95% would be an upper limit on how much radiation came back to Earth, regardless of how the model was constructed.)

But keep in mind, that's 95% of the 4% of IR that can actually be absorbed by CO2. So, what it boils down to is, Even at 100% concentration of CO2 in the atmosphere, CO2 will NEVER completely block more 3.8% of IR from reaching space.

(Oh, yeah, all of the above is also assuming that Water Vapor doesn't absorb some part of the IR in CO2's absorption range, which we know it does. I suspect that, once this is accounted for, the maximum IR absorbtion by CO2 is actually around 2%, possibly less, depending on the dsitribution of IR across the spectrum - if it's a normal probability distribution, with higher levels in the center and very small levels at the tails, then it's quite a bit less than 2%, because the 2.5-3-micron wavelengths of IR, which CO2 has to compete with water vapor for, are closer to the center of the range.)

But, more important is how this compares to the amount of IR being blocked at the "saturation point", which is about 3.1% of all IR. So, starting at the saturation point, no matter how many times you double CO2, you're never going to get more than 0.7% more IR absorption.

Of course, the key question here is, What is that saturation point? Are we exactly at that point now? If so, we can reasonably expect no more than 0.7% more IR absorption by CO2, and we'd have to increase atmospheric levels of CO2 by a factor of 8 to get there. Or perhaps we reached that saturation point sometime in the last 150 years, and are well above it now. If that is the case, then we can expect something less than that 0.7% increase. What if the saturation point was something like 200 ppm? That would mean we were already above that point before the Industrial Revolution. Today's CO2 levels are about double the saturation point, which means the atmospheric CO2 is already blocking about 3.6% of all IR from reaching space, and the absolute most that can be blocked by CO2, 3.8%, is just 0.2% more than is already being blocked.

So, does someone have the answer to that question? What is the saturation point of Carbon Dioxide with respect to IR, in PPM? At surface pressure, at what level of concentration does CO2 "absorb to extinction at its main peak"?

Of course, the other key question is, what does that mean for temperatures? If the CO2 in the atmosphere is blocking 0.7% or 0.2% more IR than it is blocking now, how much will temperatures go up?

I don't have the answers to these questions, but perhaps Coby can step in and save the day.

Posted by: Trevor | January 29, 2009 8:02 AM

14

Hi Trevor,

I commend you for taking time to try to understand what is going on! I don't have much time myself so I will just make one quick point and also ask you to reflect on two questions that reveal you have gone very wrong somewhere.

The point: incoming insolation is over 1300W/m^2 so .1% of that is a significant 1.3W/m^2 forcing.

The questions:
1. How hot is the surface of Venus and why?
2. What eventually happens to the surface temperature of the earth if anything less than 100% of reradiated energy escapes?

Thanks for your contribution!

Posted by: coby | January 29, 2009 3:09 PM

15

Coby:

I won't pretend I understand what 1.3 W/m^2 means in terms of raising temperatures. I have no idea how "significant" that is. But you're talking about INCOMING insolation. I thought the discussion here was specifically about infrared radiation absorbed and re-emitted back to the surface by carbon dioxide.

However, it heartens me to see an AGW alarmist finally admitting that even SMALL changes in insolation can have "significant" warming effects. Heretofore, alarmists have discounted the sun as the source of global warming because changes in solar output are too small to make any difference. But here you are, admitting that just a 0.1% increase in insolation creates a "significant" forcing.

As for your questions:

1. The surface of Venus is so very hot because it is CLOSER TO THE SUN than we are, and therefore receives far more insolation. Yes, the atmosphere is 96.5% CO2, but that would not make much difference, IF the surface was receiving the same amount of sunlight that Earth's does. The CO2 in the atmosphere still won't absorb any more than 4% of all infrared radiation emitted by the surface. But 4% of all infrared radiation emitted by Venus's surface is a heck of a lot more than 4% of all infrared radiation emitted by Earth's surface.

Other factors that may contribute to the Venus's warmth, but that we don't fully understand include 1) the fact that Venus has an extremely long day (longer in fact, than a Venusian year, when measured sidereally); 2) the fact that Venus rotates in the opposite direction as the Earth (and all other planets in this solar system; 3) the fact that Venus has a huge double atmospheric vortex at its south pole (the Earth has only one at each pole, of presumably smaller size than Venus's, since the Wikipedia article referred to Venus's vortices as "huge", and the vortices on Earth are known to have a huge effect on climate); and 4) the fact that Venus has a very small axial tilt (just 3 degrees, compared to Earth's 23 degrees).

2. The surface warms. And thank God, because if it didn't, the climate on Earth would be far too cold for human life. It's called the Greenhouse effect. I hope you're not trying to imply that "if anything less than 100% of reradiated energy escapes...", then we will have a RUNAWAY greenhouse effect, as apparently happened on Venus. Because if that were true, then we would have had a runaway greenhouse effect, right here on Earth, billions of years ago. Because it is now true, it was true 200 years ago, it was true 20,000 years ago, and it has been true for almost the entire history of the planet, that "less than 100% of reradiated energy escapes".

Regards,
Trevor

Posted by: Trevor | February 2, 2009 11:10 AM

16

Trevor, if insolation were the primary cause of higher temperatures on Venus, please explain why Mercury (closer to the sun and possessing a lower albedo) is several hundred degrees cooler than Venus.

Posted by: Brian D | February 2, 2009 2:00 PM

17

Trevor,

Brian has identified your misunderstandings WRT Venus and green house effects. The surface of Venus can melt lead because of its 95+% CO2 atmosphere.

You missed the point of my second rhetorical question as well. If anything less than 100% of the IR escapes the surface of the earth does not stay warm, it warms without end. This is not possible of course, which is how I am trying to show you that your attempts to quantify the effects of CO2 and prove they are saturated are wrong.

All IR must escape eventually and what increasd CO2 does is elevate the height in the atmosphere of the temperature required for this escape. This is an oversimplification but may be a useful way to understand. So the surface has to warm more and more the more CO2 in the air until a radiative balance can be reestablished. Your numbers are just wrong, having come from incorrect first principals.

You comments about the study of insolation and its effect on changing climate sow you are completely unfamiliar with the research that has been done, and also you have never looked at the IPCC report.

Try to remember that whatever the political debate is about, at its heart global warming is a scientific issue.

BTW, here is an interesting post on what is going on on Venus and why that can not happen on earth (why make that case if the scientists are "alarmists" just trying to scare people?)

Posted by: coby | February 2, 2009 3:05 PM

18

Sorry Coby but i could not resist,

Brian the fact that Mercury has very little atmosphere and therefore very little green house, is the major cause of Mercury's massive temperature swings between night and day.

It is not reasonable to compare Venus and Mercury this way, yes Venus has 97% C02 and very little of anything else, also the atmospheric pressure of Venus is something like 100 times that of Earth which influences the way C02 behaves on Venus, Venus recieves something like 3000W/m2 from the Sun, so once again you cannot compare Venus to Earth (from a greenhouse perspective).

The area Trevor is alluding to is the basis of the AGW theory and is worthy of further discussion.

This from an earlier post "Thanks for the link, interesting reading, however i was after a link which explains how the IPCC achieved thier predictions, what if any experiments were carried out and what were the results etc as opposed to a GCM."

I have not seen this data from the IPCC has anyone else? If so please post a link.

TIA

Posted by: Crakar14 | February 2, 2009 9:15 PM

19

Yes Venus recieves more insolation (I didn't check your number, you have no source cited but I don't dispute it). It also has such a high albedo due to the complete cloud cover that the surface receives less short wave radiation than the earth's surface (see link in previous comment). Shortwave radiation is the overwhelming majority of energy that comes from the sun. The reason the surface of venus is hundreds of degrees warmer than earth, despite receiving less sunlight (again at the surface) is due to its overpowering greenhouse effect.

Trevor's issue is certainly interesting, but he is extrapolating his own ignorance of it onto climate science as a whole. If you are an amateur, especially one who has not read any scientific literature on a subject, and you get results vastly different from the trained, working experts in the field, chances are pretty good it is your problem, not the rest of the world's.

Posted by: coby | February 2, 2009 10:46 PM

20

Okay, you want to get ugly? Fine.

Venus is warmer than Mercury because Mercury has virtually no atmosphere at all, and therefore no greenhouse effect. Duh! Brian D's comment is incredibly ignorant. And so is Coby for agreeing with him. The fact that Coby could read a comment like that from Brian D, and not blast it out of the water for the inanity that it is proves that Coby is just as ignorant as Brian D.

To clarify my answer to Coby's first question (I wouldn't have thought it needed clarification, but apparently I'm dealing with a bunch of ignorant people here): Carbon dioxide can NEVER prevent more than 4% of the infrared radiation emitted by the surface from escaping the atmosphere, because CO2 only absorbs IR in a very limited range of wavelengths that, together, comprise only 4% of all IR emitted by the surface. This is true on Venus as well as Earth. However, 4% of Venus's IR emissions is a hell of a lot more than 4% of Earth's IR emissions, because Venus's surface receives much more solar radiation than Earth's. And therefore, Venus's surface is much warmer than Earth's. Meanwhile, Venus's surface is also much warmer than Mercury's because Mercury does not have a greenhouse effect at all. (However, it's worth noting that Mercury, with no greenhouse effect at all, is, on average, still much warmer than Earth.)

And to respond to Coby's response to Crakar:

Venus's albedo is 60%; Earth's is 30%. So, even if insolation was measured in the upper atmosphere, Venus's 3000 W/m^2 results in a net 1200 W/m^s at the surface, while Earth's 1366 W/m^2 results in just 956 W/m^2 at the surface. But insolation is not measured in the upper atmosphere, but at the SURFACE. That means that the 3000 and 1366 W/m^2 are already taking albedo into account. So, Venus's surface receives over twice as much insolation as Earth's. Now, I understand that Venus's surface is DIMMER than Earth's, but that only means that it receives less VISIBLE light from the sun. And I don't know where you got your figures, Coby, but my source says that only about half of all solar radiation is in the visible, short-wave part of the spectrum. So the additional insolation on Venus is clearly coming from other parts of the spectrum. Venus has a very weak magnetic field compared to Earth's, and we know that Earth's magnetic field partially shields it from solar radiation. Venus clearly doesn't have as much of this shielding as Earth.

But while we're talking about Venus, the very article you referenced, Coby, clearly states that Venus's runaway greenhouse effect was caused by WATER VAPOR, not carbon dioxide. The same article says this is not a possibility on Earth. But, more importantly, unless you believe that little green men were driving big green SUVs around Venus's surface 4-5 billion years ago, global warming on Venus clearly was not caused by anthropogenic (or should I say say xenogenic?) emissions of CO2 due to the burning of fossil fuels.

As for your second question, I was initially confused by your parsing of words here. Yes, every individual ray of IR will, EVENTUALLY, escape Earth's atmosphere (although, since we're parsing words here, even that is not TECHNICALLY true - see footnote). But that's not the issue. The issue is what percentage of the IR emitted by the surface is, at any given time, bouncing around in the atmosphere, where it can eventually return to the surface and cause warming. In that sense - the sense I was referring to, and the only sense that matters - carbon dioxide can "trap" no more than 4% of all IR emitted by the surface. But it does trap some IR, and in the sense I'm using the word, that portion that is trapped is prevented from "escaping" the atmosphere. And of course, on top of that, there is all the IR that is "trapped" by water vapor and the minor greenhouse gasses. None of this IR "escapes" the atmosphere, in the sense that I'm using the word (again, the only sense that matters in this discussion). And yet, we do not have a runaway greenhouse effect, which, by your logic, we WOULD, if as little as 0.000001% of all IR was prevented from escaping the atmosphere. But then, you're using the word "escape" in a different sense, one that is irrelevant to the discussion.

As for your final comment, "If you are an amateur, especially one who has not read any scientific literature on a subject, and you get results vastly different from the trained, working experts in the field, chances are pretty good it is your problem, not the rest of the world's.":

So, the "chances are pretty good" that Svante Arrhenius, T. C. Chamberlin, and Guy Callendar were WRONG, when they insisted, a century ago, that Carbon Dioxide could cause global warming, despite the fact that virtually every meteorologist and climatologist disagreed with them. These guys were all "amateurs" in the respect that, though they were scientists, they most certainly were not climatologists. And all of the "experts" in the field, the REAL climatologists, said they were full of crap. These are the guys that the alarmists hold up as the pioneers of global warming research. Yet by the standards they are applying to global warming skeptics, no one should have ever listened to these amateurs.

Oh, and your "trained, working experts" wouldn't be working at all if there weren't hundreds of billions of dollars of government funding being thrown at researching this "problem". And if it were ever established that anthropogenic global warming is wrong, that money would dry up very quickly. So tell me, Coby, with a straight face, that your "trained, working experts" don't have a vested interest in promoting fears of anthropogenic global warming.

Regards,
Trevor

Footnote: Since we're parsing words and getting technical about IR "escaping" the atmosphere; the only IR that ever truly "escapes" the atmosphere is the IR that goes clean through the entire atmosphere without ever encountering a molecule of greenhouse gas that could absorb it. Any IR ray that does encounter such a GG molecule will be immediately absorbed, and its energy will be transferred to the molecule itself. This IR ray effectively CEASES TO EXIST at this point, WITHOUT EVER HAVING "ESCAPED" THE ATMOSPHERE. Now, the GG molecule will, of course, emit ANOTHER IR ray, in a random direction, and THAT IR ray MIGHT escape the atmosphere. But that new IR ray is not the SAME IR ray as the one that was absorbed. The original IR ray, the one that was absorbed, is simply GONE. It did not escape, any more than a prisoner who, in attempting to escape, is shot and killed before he gets over the fence.

Posted by: Trevor | February 3, 2009 9:42 AM

21

Posted by: Brian D | February 2, 2009 2:00 PM:

"Trevor, if insolation were the primary cause of higher temperatures on Venus, please explain why Mercury (closer to the sun and possessing a lower albedo) is several hundred degrees cooler than Venus."

Well, duh! Mercury is cooler than Venus because mercury has very little atmosphere, and no significant greenhouse effect at all. Your post displays your incredible ignorance of atmospheric science. It is the COMBINATION of insolation and greenhouse effect that makes Venus so much hotter than both Earth (greenhouse effect, but not as much insolation) and Mercury (a lot of insolation, but no greenhouse effect).

However, if you think that insolation ISN'T the primary cause of planetary warmth, then please explain why Mercury, WITH NO GREENHOUSE EFFECT AT ALL, is still, on average, warmer than Earth.

Regards,
Trevor

Posted by: Trevor | February 10, 2009 9:56 AM

22

One more thing, Coby.

As the article you referenced regarding "what's going on on Venus" explains, Venus's runaway greenhouse effect was caused by water vapor, not carbon dioxide. It MIGHT be said that, at the present time, carbon dioxide is MAINTAINING a very high temperature on Venus's surface. But carbon dioxide most certainly is not CAUSING warming on Venus. There's no warming going on there right now, is there? The warming that DID occur, billions of years ago, was due to water vapor. The only thing the carbon dioxide is doing is maintaining the temperatures established long ago by the water-vapor-initiated runaway greenhouse effect.

Now, again, I'm no expert on atmospheric science, (though clearly more knowledgeable than Brian D; and I'm beginning to think you're just as ignorant as Brian D, since you endorsed his comment about the reason Mars is cooler than Venus). But it seems to me that it is much, much easier to MAINTAIN a certain temperature level than it is to initiate a CHANGE from one temperature level to another. Think about the heating system in your home. It takes a whole lot more energy to WARM your house from 10 degrees C to 20 degrees C than it does to KEEP your house at 20 degrees C once that temperature has been reached.

In fact, I believe my own home's heating system is very analagous to Venus's greenhouse effect. I have a two-stage heat pump. As long as I'm just maintaing a given temperature (set by the thermostat), the "normal" heat pump action, with only-slightly-warmer-than-current-temperature air, is sufficient for that purpose. However, if I set my thermostat to two or more degrees (F - my thermostat isn't metric) warmer than the current temperature, the "supplemental heat", or "second stage heating", will kick in. This supplemental heat blows out HOT air, warming the home quickly, until the temperature reaches that set by the thermostat. At that point, the "normal" heat pump action takes over.

In this analogy, the "normal" (or first-stage) heat pump action is the carbon dioxide greenhouse effect on Venus, while the "supplemental" (or second-stage) heat is the much-more-powerful original, runaway, water-vapor-initiated greenhouse effect.

Of course, I admit that this "greenhouse effect maintenance" probably does not FULLY explain the difference between Earth's and Venus's surface temperatures. I doubt that Carbon Dioxide could even MAINTAIN temperatures that warm, here on Earth, even if they ever got that high to begin with. Why? BECAUSE EARTH DOESN'T RECEIVE NEARLY AS MUCH SOLAR ENERGY AS VENUS.

Regards,
Trevor

Posted by: Trevor | February 10, 2009 11:13 AM

23

Trevor,

It is very difficult to debate this point using the approach you have chosen, for every science paper you produce to validate your position Coby and Brian could produce one to validate theirs. This to me would suggest the science is not in on this particular issue.

Instead i would suggest you look at a way of measuring the effects of increased C02 in the atmosphere, for example the IPCC consensus states (in simple terms) increased C02 will be seen as a heat increase or warming about 10K's up above the tropics commonly known as the "hot spot". Therefore if the atmosphere is warming more than the surface then C02 is affecting the climate. If no "hot spot" can be found then C02 has no effect and AGW theory is dead in the water.

Currently there are two independant sources for measuring the warming or lack thereof, they are radiosonde weather balloon and satellite. I suggest you take a look at this data you might find it of interest.

Cheers

Crakar14

Posted by: Crakar14 | February 10, 2009 10:12 PM

24

Crakar:

Thanks for the advice. Though I have not DIRECTLY looked at this data you recommend (can you provide a link?), I have seen articles pointing out that both the weather balloon and satellite records of atmospheric temperatures confirm that the atmosphere is actually warming MORE SLOWLY than the surface. As you point out, this is a direct contradiction to AGW theory, which states that the atmopshere should warm more rapidly than the surface.

I can't seem to find this skeptic argument against AGW listed among the arguments that Coby refutes on this site. However, I have seen other alarmists confront this argument by claiming that, after certain "adjustments" were made to the satellite data, it does indeed show slightly more warming in the atmosphere than at the surface. What I find very interesting is that the organization responsible for these "adjustments" is NASA's Goddard Institute for Space Studies, whose director is none other than James Hanson, Al Gore's "scientific advisor".

Regards,
Trevor

Posted by: Trevor | February 11, 2009 5:06 AM

25

Crakar:

Though it appears we are on the same side here, I have to take issue with one of your statements:

"It is very difficult to debate this point using the approach you have chosen"

I beg to differ. It appears to me that the approach I have chosen has been quite effective. There hasn't been a single post from Coby, Brian, or any other AGW alarmist since I picked apart their arguments in my Feb 3 post. I particularly enjoyed hoisting Coby on his own petard regarding his parsing of the phrase "escape the atmosphere". But what it all comes down to is that CO2 cannot possibly block any more than 4% of IR from escaping the atmosphere (I give credit to you for that 4% figure, but I'd like to know where you got it from, in case I need to use it somewhere else). Coby's just trying to confuse us with this "elevate the height in the atmosphere of the temperature required for this escape" nonsense. It still doesn't change the IR absorbtion wavelength bands of carbon dioxide. And if all of the IR in those bands is already being blocked, by either CO2 or water vapor, then CO2 cannot possibly cause any further warming, at ANY altitude.

I wonder where Coby has gone. Surely he has seen my post. Does he not have an answer for it? I mean, if nothing else, he could just pop in and call me "ignorant" again; say I don't understand the science and that the rest of the world disagrees with me. But like Arrhenius, Chamberlin, and Callendar, I'm not going to just go away because the entire climatology community disagrees with me. What I would really like to know is, where the hell were all these proponents of the "scientific concensus" when the concensus was that mankind could not affect the climate, and guys like Arrhenius, Chamberlin, and Callendar were the "deniers"?

Regards,
Trevor

Posted by: Trevor | February 11, 2009 6:27 AM

26

Trever, I've read your posts here and I wouldn't expect a reply from Coby any time soon. It has nothing to do with the quality of your arguments, which are rambling at best. It's your tone.

Your posts are sarcastic, arrogant and insolent and your disgust with people who disagree with you is obvious. So don't confuse silence from others with a winning argument. They are ignoring you...

Posted by: mikatollah | February 11, 2009 1:02 PM

27

Trevor,

Rather than debate the science behind an issue that is not entirely understood by all, you could look for and debate the evidence to support your position.

Have a read of this story paying attention to the part about radiosonde data.

http://www.theaustralian.news.com.au/story/0,25197,24036736-7583,00.html

Cheers


Posted by: Crakar14 | February 11, 2009 4:33 PM

28

Mikatollah:

Sarcastic, arrogant, and insolent my posts might be. But if you will look back at the history of the discussion on this topic, you will clearly see that Coby called me "ignorant" at one point. THAT was when I responded in kind. So who, pray tell, has a problem with "tone"? Of course, I can add you to that list now, as you have called my arguments "rambling", rather than attempting to refute them. By the way, the least you could do is spell my name right.

No, it's quite clear that Coby is not responding because I have thoroughly embarrassed and discredited him. He seconded Brian D's "identification" of my "misunderstandings WRT Venus and green house effects", which completely ignored the fact that Mercury has no greenhouse effect. Brian's comment was ignorance of the highest order, and Coby fully endorsed it.

Now, personally, I wouldn't have thought that Coby was really that ignorant, and I was initially willing to give him the benefit of the doubt on this one, and write if off to Coby's unwillingness to humiliate someone on his own side, even though he knew Brian was dead wrong. But then, when Coby made the statement that "If anything less than 100% of the IR escapes[,] the surface of the earth does not stay warm, it warms without end" and "All IR must escape eventually", I knew that Coby really didn't have a clue about how the greenhouse effect works. As I clearly explained in the footnote of one of my posts, any IR that is absorbed by a greenhouse gas molecule ceases to exist at that point, WITHOUT EVER ESCAPING THE ATMOSPHERE. The fact that the GHG molecule emits ANOTHER ray of IR doesn't change the fact that the ORIGINAL IR ray is dead and gone.

Regards,
Trevor

Face it, mikatollah - Coby is just dead wrong on this. His incoherent statement about "increasd CO2 ... elevat[ing] the height in the atmosphere of the temperature required for this escape" (what in the hell is the height of the temperature? That's just nonsense.) is no more than a very lame attempt to steer the discussion away from the fact that CO2 can never, EVER trap, for ANY amount of time, more than 4% of the Infrared Radiation emitted by the surface.

Posted by: Trevor | February 12, 2009 5:45 AM

29

Trevor,

Sorry about misspelling your name... it was inadvertent.

You can tell a lot about a person from their blog postings. So much so that businesses and government have begun personal searches on people requesting jobs and security clearances. I tell my kids to be mindful of their tone and manners online because people are watching and it could come back to haunt you.

As for your technical argument, the CO2 molecule saturation argument against AGW has been around for years and has been discounted by climate scientists and answered on several web sites so you are not going to change any minds with it here.

You do tend to ramble when you are trying to make a point about Venus or gas molecule saturation. You wrote 30 or 40 paragraphs about it in a thread about AGW theory and the second law of thermodynamics. A bit off topic.

Posted by: mikatollah | February 12, 2009 8:52 PM

30

[Introductory Note: I composed my comments below offline, a few weeks ago, in response to the very first post above, soon after coming across this site. Some of the comments in response to "Shane" are relevant to the discussion following, which has developed since my last visit here. In particular, the "4%" figure needs to be justified by some of the posters, like Trevor, who does not say where the 4% figure comes from.]
The comments by Shane at the first post above are misleading, confused, and ill-considered. It is a set problem in certain textbooks on atmospheric physics (see, e.g., John Houghton’s The Physics of Atmospheres) to work out the incremental fraction of radiation absorbed by CO2 in the 15-micron band, e.g., for a doubling of CO2. When the CO2 concentration of the atmosphere is doubled, the change in the outgoing top-of-atmosphere (TOA) radiation is about 4 W/m^2 (in the absence of feedbacks). The corresponding TOA temperature change, from the Stefan-Boltzmann law, would be about 1 K, with no additional feedbacks. I suggest Shane work through this kind of set problem, to convince himself of this. Shane also appears to confound the issues by multiplying the CO2 abundance by the fraction of the total radiation that is available for absorption by CO2. This is a gross mistake. The CO2 can, if concentrations are high enough, absorb ALL the radiation, in the relevant spectral ranges. The relevant quantity would be 100% of 4%, not CO2’s “share” of the total atmopheric gas concentration multiplied by 4%. Shane should have a look at Fig. 3.14 in An Introduction to Atmospheric Physics by David G. Andrews, in which are shown the IR absorption spectra for 6 strongly absorbing gases, including water vapour and CO2, for a vertical beam passing through the atmosphere. He will notice that CO2 absorption is practically complete in the spectral interval 13.5 to 16.5 microns, and remains substantial beyond these values, out to ~13 and ~18 microns.
I also question the “4%” in Shane’s claim that “…the band widths that are absorbed are less than 4% of the black body radiation emitted back into space.” If one looks at the Planck distribution for a temperature of 255 K, which is the equivalant blackbody temperature corresponding to the net longwave radiation to space of the Earth (240 W/cm^2), then it is quite clear that the fraction of the total radiation falling within the range of wavenumbers that can be absorbed by CO2 is much higher than 4%. In his book Radiative Heat Exchange in the Atmosphere, p.128, Kondratyev writes that “…the entire absorption band centred at 14.7 microns causes an absorption of 14% of the black body radiation.” This figure appears to be an underestimate, as it ignores the far wings of the band, and should be closer to 20%. (See Kondratyev’s Table 17.) If Shane were to find a Planck-function calculator (these can be found on the net), and look at the distribution for our 255 K blackbody, he will see that more than 40 W/m2 of the total flux of 240 W/cm^2 falls in the interval 13 to 17 microns. This is because this spectral interval falls close to the peak of the blackbody curve. Note that most of the radiation in this 15 (+/-2)-micron interval has already been absorbed by the already-existing CO2. If we were to remove all the CO2 from the atmosphere, we would get a much bigger temperature drop (something like 7 K) than would be observed as an increase upon doubling from the present value. I wonder if Shane is confusing the canonical 4 W/m^2 (for forcing due to CO2 doubling) with a percentage…..
By the way, some of the folk here might like to learn how to spell "absorption".

Posted by: Peter Doidge | February 16, 2009 6:15 PM

31

My second comment here is addressed directly to Trevor’s claim that: “I note that no one has addressed Shane's comment, other than "notes", who can only say, "... carbon dioxide absorbs to extinction at its main peak ...". The key phrase there, notes, is "at its main peak". Carbon dioxide absorbs Infrared Radiation (IR) only at two very narrow ranges of wavelength, one between 2.5 and 3 microns, and another between 4 and 5 microns.”

The last claim here is incorrect. As Kondratyev’s discussion, in the book mentioned above, makes clear, the two main absorption bands of CO2 fall at 4.3 and 14.7 microns. He writes (p.122): “Apart from these two main bands, there are also bands centred at wavelengths of 2.7 and 10 microns, and also a number of other weak bands.” HOWEVER, “…the 2.7 and 4.3 micron bands are located far from the centre of the spectral distribution curve of black body radiation at atmospheric temperatures; consequently their effect on the absorption of the long-wave radiation of the earth in the atmosphere can be ignored in spite of the second of these bands being quite intense.”

Posted by: Peter Doidge | February 16, 2009 6:38 PM

32

Peter,

Thanks for adding a more technical approach to the debate, one question, you refer to the term "black body" quite a bit. Am i to assume that all the facts and figures you have supplied here are from laboratory and computer modelling results?

If so are you aware of any real world experimentation that can accurately show how C02 reacts to the IR at the relevant frequencies and how the C02 behaves in the presence of water vapour?

You also quote figures based on the absence of feed backs what effects would feed backs have on the data you have supplied.

Cheers

Crakar

Posted by: Crakar14 | February 16, 2009 8:03 PM

33

Peter:

FYI, I was aware of the 14.7-micron band of CO2 absorption. But it seemed to me, that if the IR emitted from the surface followed anything like a "normal probability distribution" curve, centered anywhere near the "central" wavelengths of what we call "infrared radiation", then this 14.7-micron wavelength was in the extreme tail of the distribution, and there would be a vanishingly small amount of IR there. That was the assumption that I made, since I don't have access to the ACTUAL distribution of IR emitted by the surface. And under that assumption, the 4% quoted by Shane seemed very reasonable, though I confess, as I have all along, that I don't know where Shane's number came from.

Now, if you, Peter, have some source for the ACTUAL distribution of IR emitted by Earth's surface, I would be glad to take a look at it. And if it confirms that the distribution of IR emitted from the surface is something other than a normal distribution, or that the center of that distribution is closer to the 14.7-micron band, then I will have to adjust my analysis accordingly. However, none of this changes the fact that Coby is still dead wrong. Whatever the maximum percentage of IR that can be absorbed by CO2 is (whether it's closer to your 20% or Shane's 4%), it cannot be changed by Coby's ridiculous claim that "If anything less than 100% of the IR escapes[,] the surface of the earth does not stay warm, it warms without end" or his nonsense about CO2 "elevat[ing] the height in the atmosphere of the temperature required for this escape".

Regards,
Trevor

Posted by: Trevor | February 18, 2009 6:12 AM

34

Mikatollah

"Sorry about misspelling your name... it was inadvertent."

Apology accepted.

"You can tell a lot about a person from their blog postings. So much so that businesses and government have begun personal searches on people requesting jobs and security clearances. I tell my kids to be mindful of their tone and manners online because people are watching and it could come back to haunt you."

All well and good, but totally irrelevant to the topic at hand. But then, you AGW alarmists like to change the subject a lot, don't you? And I must reiterate that Coby was the first to become condescending, when he called me "ignorant". When, in fact, if he could endorse the comments of Brian D, then directly spout his own nonsense, it is Coby who is supremely ignorant.

"As for your technical argument, the CO2 molecule saturation argument against AGW has been around for years and has been discounted by climate scientists and answered on several web sites so you are not going to change any minds with it here."

If so, then perhaps you could provide a link to such a site. Preferrably one that doesn't use the same nonsense Coby has been spouting.

"You do tend to ramble when you are trying to make a point about Venus or gas molecule saturation. You wrote 30 or 40 paragraphs about it in a thread about AGW theory and the second law of thermodynamics. A bit off topic."

Counting paragraphs, are you? Well, apparently, 30 or 40 isn't enough because you guys STILL don't get it. As for the off-topic part, perhaps if Coby had devoted a separate page to this topic, then this discussion could be moved to that page. But, apparently, Coby isn't as confident in his ability to "refute" this argument as in his ability to refute easy arguments like "Its cold today in Wagga Wagga", "Global warming comes from all that heat at the Earth's core", or "We Can't Even Predict the Weather Next Week". And the discussion here shows he is right to lack that confidence.

Regards,

Trevor

Posted by: Trevor | February 18, 2009 6:34 AM

35

So we are still playing AGW denier whack-a-mole. Coby has already directed you to a discussion of the gas absorption issue and its history, but here it is again for anyone interested enough to do a little reading:

http://www.realclimate.org/index.php/archives/2007/06/a-saturated-gassy-argument/langswitch_lang/wp

If you are still interested in debating specific scientific points, I think Peter is preparing to take you to school.

Posted by: mikatollah | February 18, 2009 9:02 AM

36

Mikatollah.

Thanks for the link. I had seen it before but discounted it as misleading. And it is. Just because it appears, in print, on some AGW alarmist website doesn't make it a fact. You see, the article only pays lip service to the IR absorption bands of CO2, then goes into this same gobblydegook about elevating the height in the atmosphere where the heat escapes. When are you guys going to get it through your heads that there's only so much IR that can be absorbed by CO2, no matter how much CO2 there is or where it is in the atmosphere?

Look, if you have a city with a population of 1,000,000 and 1,000 crimes are committed each day, you would like to lock the criminals up. So you hire cops to arrest the criminals. But a cop can only arrest, say, 10 people per day. So, if you hire 100 cops, and distribute them evenly around the city, that's enough to arrest all 1,000 of the criminals. Hiring another cop won't get you any more arrests, because there aren't any more criminals. Now, if you want to complicate things, you can say that half of the handcuffs in the town are faulty, and half of all arrests result in the criminal escaping. So, yes, if 500 of the original 1,000 arrestees escape, hiring another cop will net you another 5 arestees. And yes, more and more cops will result in more and more NET arrests. But you're NEVER going to have more than 1,000 people locked away in jail. No matter WHERE you put the additional cops. Unless you start arresting innocent people.

If you look closely at the article, it provides clues as to where it's misleading you. It ADMITS that the air is thin in the upper atmosphere. But what it neglects to mention is that this means that carbon dioxide molecules, even if they were just as highly concentrated as in the lower atmosphere, are still few and far between. Additional carbon dioxide at such high altitudes is a drop in the bucket.

The article goes on to mention that the absorption bands of all the greenhouse gasses narrow at higher altitudes. This is mentioned in the hope of minimizing the "overlap" effect of water vapor. But if you think about it, it also means that whatever percentage of IR can be absorbed by CO2 in the lower atmosphere, that percentage is significantly lower at higher altitudes. How much lower? The article doesn't say. Probably because the author wants to leave the reader with the assumption that it's just enough to zero out the overlap effect of water vapor without significantly affecting the direct absorption by CO2.

Finally, the article attempts to mislead the reader into believing that a 1% increase in the earth's "radiation balance" is equivalent to a 1% increase in the earth's temperature. To be fair, the article doesn't exactly SAY this, but it puts the two together in such a way that a less-informed reader would obviously make such a connection. And after all, the "less-informed reader" is the target audience of this article.

But at least now I understand where the "temperature" part of Coby's nonsensical statement about raising the height necessary for escape comes from. Apparently, the theory goes like this. More CO2 in the atmosphere means more CO2 in the upper atmosphere. This (despite, somehow, the air being much thinner at that altitude, and the absorption bands much narrower) means that the level at which IR "escapes" the atmosphere is higher than it would be if there were less CO2. And the atmosphere at this level is colder than at the level the IR would have escaped at if CO2 levels were lower. So, the heat lost to space is lower. Okay, I get it now. I failed to grasp this earlier because of the ridiculous assumptions behind it. Allow me to dash those assumptions. Here goes. 1) IR "escapes" from the atmosphere at the same altitude, regardless of how much CO2 is present or where. More CO2 in the upper atmosphere doesn't make the atmosphere thicker. 2) It doesn't even matter what altitude the IR escapes at, or what the temperature of the atmosphere is at that altitude. It isn't the atmosphere that is escaping. It's the IR rays. Infrared radiation IS heat. A "unit" of infrared radiation has the same energy (heat) in the upper atmosphere as it does at the surface, and that amount of heat is not affected by the temperature of the surrounding air. This whole argument about the temperature of the atmosphere at the level where IR escapes is a red herring. If a unit of heat escapes, it escapes, and the heat balance goes down one unit, regardless of what the air temperature was at the altitude the unit of heat escaped. Just another attempt to mislead the uninformed.

Regards,
Trevor

Posted by: Trevor | February 19, 2009 1:13 PM

37

You know Trevor, there is an old Steve Martin joke about how funny it would be if you taught a small child the wrong meaning for simple words. Then when he finally gets to go to school, he raises his hand and asks his teacher, "Can I mambo dogface in the banana patch?"

What you are doing here is attempting to make readers mambo dogface in the banana patch...

So we have to choose. Do we believe peer reviewed climate scientists whose only agenda is to get the science right, or do we believe the angry blogger who is scared his tax bill might go up...That is why I said earlier that you are not going to change any minds here with old arguments.

Your arguments have been debunked generally in the realclimate posting, and specifically among the 248 responses that followed. This mole has been whacked.

Posted by: mikatollah | February 19, 2009 2:45 PM

38

Craker,
Thanks for your response. You write:
“Am i to assume that all the facts and figures you have supplied here are from laboratory and computer modelling results?”
Not at all. The numbers I quoted were mostly from the textbooks I cited. These are (usually) written to give students (and I count myself a student in this field; I am no kind of “expert” in most of the sub-disciplines of climate science) a feel for the magnitudes of the effects. The Kondratyev book I cited is slightly different, having been written in the 1960s to summarise (probably for a largely Soviet readership) some of the results of then-recent findings in the field. Some of those papers are now rather dated. However, the underlying principles of the spectroscopy of CO2, as set out in this book and others, remain valid.

As to “real world experimentation that can accurately show how C02 reacts to the IR at the relevant frequencies”, I think it is one of the more persistent “mythconceptions” advanced by “skeptics” that our notions about atmospheric response to increased CO2 come only from climate modeling, or laboratory measurements. In fact, there is direct evidence, which appears (to my non-specialist eye) to be quite good, from satellite observations dating back to 1970, that the spectral “signatures” of the outgoing longwave radiation have changed, between 1970 and the present day. See, for example, J. A. GRIGGS and J. E. HARRIES, Comparison of Spectrally Resolved Outgoing Longwave Radiation over the Tropical Pacific between 1970 and 2003 Using IRIS, IMG, and AIRS, J. Clim., v. 20, p. 3982 (2007). From the abstract: “The observed difference spectrum between the years 2003 and 1970 generally shows the signatures of greenhouse gas forcing, and also shows the sensitivity of the signatures to interannual variations in temperature.”
I don’t know if this paper is available for free download- I think I had to go to my local university library to get it- but you can see some of this group’s results at this page: http://www.eumetsat.int/Home/Main/Publications/Conference_and_Workshop_Proceedings/groups/cps/documents/document/pdf_conf_p50_s9_01_harries_v.pdf

My attention has been drawn back to Trevor, through new posts of his, so I must respond on water-vapor at some other time.

Posted by: Peter Doidge | February 19, 2009 6:25 PM

39

Trevor: I disagree with practically everything you’ve written in your latest posts.
First, I do not understand why you refer to the radiation distribution as a "normal probability distribution" and go on to refer to a “…curve, centered anywhere near the "central" wavelengths of what we call "infrared radiation".” The Planck radiation distribution (which describes reasonably well the distribution of incoming solar radiation, and that of the upgoing radiation from earth’s surface) is not “normal”. It is not “centered” in the way you appear to mean. It is peaked, but does not behave like a normal, or Gaussian, distribution, which is what I take you to mean. The area under the Planck distribution is not the same for equal frequency intervals at equal distances either side of the peak. It is not symmetrical in that sense.
Your comments about the 15-micron CO2 band also lead me to suspect that you do not understand that the peak of the outgoing radiation curve is VERY different from that of the incoming solar flux. But this is basic bread-and-butter textbook stuff. Incoming solar radiation is approximately “black”, with a brightness temperature of about 5800 K. The radiation going upwards from the earth’s surface is also black, with a blackbody temperature of about 288 K. Again, this is textbook stuff. You asked me if I “… have some source for the ACTUAL distribution of IR emitted by Earth's surface”. Have a look in texts by Houghton, Goody, and others. I can’t do your homework for you, Trevor. You have to show a willingness to learn. Unfortunately, this willingness to learn from such material as textbooks appears all too often to be absent among the “skeptic” contributors at sites such as this. You continue to push the “4%” value from Shane, though you produce no physical arguments yourself to support it, neither do you produce arguments as to why the numbers I’ve quoted from textbooks are wrong.

From Wien’s displacement law, which relates the wavelength at peak to the inverse temperature, and since the peak of the solar radiation is about 0.6 microns, then the peak of the surface radiation would be at about (5800/288)*0.6 microns, or about 12 microns. This is close to the peak of the CO2 bands. It is certainly not the case that “…this 14.7-micron wavelength was in the extreme tail of the distribution”. It also means that a large part of the IR “window” region, from 8 to 13 microns (where the atmosphere is largely transparent, owing to lack of absorption by H2O or CO2) falls close to the peak of outgoing radiation.

You question the argument in the Weart-Pierrehumbert article about “saturation”, simply because it is published at an “AGW alarmist” site (your words). You also issued a challenge: “If so, then perhaps you could provide a link to such a site. Preferrably one that doesn't use the same nonsense Coby has been spouting.”
Would it surprise you to know that Weart published much of the material and argument in the online article in an article published in Physics Today, the American Physical Society’s house journal? Weart’s material is also available online at APS, if you care to look. But perhaps you think APS is an “AGW alarmist”. Have a look at what one of Weart’s sources, Gilbert Plass, had to write, in the 1950s: “The argument has sometimes been advanced that the CO2 cannot cause a temperature change at the surface of the earth because the CO2 band is always black at any reasonable concentration. This argument is true for the lines near the centre of the band from 14 to 16 microns, but neglects completely the important contribution of the lines farther from the band centre”. (Plass, G.N. (1956). "The Influence of the 15-micron CO2 Band on the Atmospheric Infra-Red Cooling Rate", Quarterly J. Royal Meteorological Society 82: 310-29.) This basically re-states, and refutes, the “saturation” argument that had been advanced by scientists for several decades. I don’t have a link to a site for the text of this article, Trevor, but you are most welcome to follow it up, at a good library.
You also question the physical basis of the effect whereby increasing CO2 changes the height in the atmosphere corresponding to the effective emission temperature. Here is what the atmospheric physicist John Houghton had to write, in responding to Jack Barrett’s misconceptions, as set out in an article in Spectrochimica Acta, Part A: “In fact, most of the enhanced greenhouse effect occurs not because of changed absorption of radiation from the surface (although some change does occur in the wings of the carbon dioxide band where absorption is weaker) but because as the concentration of carbon dioxide in the atmosphere increases, the average height (around 6 km) from which carbon dioxide emits radiation to space also increases. Since atmospheric temperature in the lower atmosphere falls with altitude, if nothing changes other than the amount of carbon dioxide, the amount of radiation to space is reduced. For atmospheric carbon dioxide this reduction can be accurately calculated [my emphasis]; for doubled atmospheric concentration it is about 4 W m^-2. To restore the Earth’s energy balance the temperature throughout the lower atmosphere has to increase - hence the enhanced greenhouse effect.” [Spectrochimica Acta Part A, v.51 (1995) 1391- 1392]
Again, this is bread-and-butter stuff, Trevor. If you don’t understand, then I doubt there’s much more I can say.
Cheers

Posted by: Peter Doidge | February 19, 2009 10:14 PM

40

I cannot resist taking a swipe at one or two more of Trevor's arguments.
(1) Trevor:"The article goes on to mention that the absorption bands of all the greenhouse gasses narrow at higher altitudes. This is mentioned in the hope of minimizing the "overlap" effect of water vapor. But if you think about it, it also means that whatever percentage of IR can be absorbed by CO2 in the lower atmosphere, that percentage is significantly lower at higher altitudes."
No, the lines become narrower AND taller (i.e., have greater absorption coefficients). The reduced collisional (and Doppler) broadening at higher altitudes means the lines become narrower, but if the line strength stays the same (it does vary slightly with temperature, for CO2), the AREA under the absorption vs frequency curve remains contant. HOWEVER, and this is also part of the Weart argument, the amount of water vapour at the top of the atmosphere is very small. (Remember the freezing point of water?) The radiative effects up there are dominated by CO2, ozone, and other gasses that remain gases below the f.p. of water, and not so much by water vapour.

Posted by: Peter Doidge | February 19, 2009 10:34 PM

41

Trevor: Finally, the article attempts to mislead the reader into believing that a 1% increase in the earth's "radiation balance" is equivalent to a 1% increase in the earth's temperature. To be fair, the article doesn't exactly SAY this, but it puts the two together in such a way that a less-informed reader would obviously make such a connection. And after all, the "less-informed reader" is the target audience of this article.

Actually, Trevor, I agree with your first sentences here, but disagree with the very last one. (To the contrary, it appears to me that Weart-Pierrehumbert aim to educate a quite sophisticated audience.) A 1% change in radiative forcing (power) does not equate to a 1% temperature change. I might not have preferred to express matters that way myself.
Cheers

Posted by: Peter Doidge | February 19, 2009 10:50 PM

42

As a general comment, I have been trying to avoid GW blogs for some time, as (1) they seem to descend rapidly into name-calling, and (2) I don’t have much time anyway. But, as Al Pacino once said, “Just when I’m out, they pull me back in”. So here I am. I have a comment on Trevor’s claim to have been called “ignorant”. I think that if Trevor reads Coby’s post again, he’ll see that Coby wrote of (what he took to be) Trevor’s “ignorance of” [an issue]. Now, to my way of thinking, saying someone is “ignorant of [some field or topic, or issue]” is not the same as saying that person is “ignorant” (which means, of course, totally ignorant).

Posted by: Peter Doidge | February 19, 2009 11:35 PM

43

Peter (as quoting John Houghton)

"... as the concentration of carbon dioxide in the atmosphere increases, the average height (around 6 km) from which carbon dioxide emits radiation to space also increases. Since atmospheric temperature in the lower atmosphere falls with altitude, if nothing changes other than the amount of carbon dioxide, the amount of radiation to space is reduced."

Okay, someone has finally stated this in a way that, at least on the surface, makes sense. But it is still misleading. Atmospheric temperature falls with altitude only because the atmosphere there is less dense (and therefore IR-absorbing greenhouse gasses are more rare). But if there's more carbon dioxide up there, absorbing more infrared radiation, then there's also more heat at that level of the atmosphere. So, although the "average height ... from which carbon dioxide emits radiation to space" increases, the average temperature at that height also increases, to exactly the same temperature as at the lower average height from which CO2 formerly emitted radiation to space. So it's still emitting radiation at the same temperature.

"No, [at higher altitudes,] the lines [absorption bands]become narrower AND taller (i.e., have greater absorption coefficients)".

Okay, here is where you have a chance to convince me. You see, my source on absorption spectra for the major greenhouse gasses (avaliable online at http://www.climate-skeptic.com/2007/09/chapter-3-skept.html) is a graph that shows an absorptivity of 1 for carbon dioxide over three separate ranges of wavelengths (between about 2.5 and 3 microns, 4 and 4.7 microns, and 13.5+ microns). The important point is that for the graph I have been looking at, absorptivity is ALREADY AT 1, or 100% if you prefer to express it that way. You cannot have an absorptivity of greater than 1. Of course, I'm assuming that the terms "absorptivity" (at least as used by my source) and your "absorption coefficient" have the same meaning, and if that is not the case, feel free to enlighten me. Or perhaps you believe the graph I've been looking at to be wrong in some way, in which case you can hopefully point me to some source that shows absorption coefficients of less than 1, at the CO2 peaks, in the lower atmosphere. Otherwise, I would love to hear how carbon dioxide in the upper atmosphere can achieve an absorption coefficient of greater than 1.

Regards,
Trevor

Posted by: Trevor | February 24, 2009 8:42 AM

44

You guys seem to want to talk about Venus a lot. The main reason for its high temperature is glaringly obvious. The atmospheric pressure on Venus is huge. Simply huge. Ninety two times larger than it is on Earth at surface level. Remember PV = nRT? Think about it. Temperature increases with pressure. That's why Venus is so hot. The greenhouse effect has very very little to do with it. The simple fact that pressure being something other than zero requires a temperature seems too often forgotten. One sees the 33oC figure tossed around a lot... and it is all assumed to come from the greenhouse effect. How silly! surely a large portion comes from the simple pressure itself! And of course a fair bit also comes from convection; contact with the warm surface of the Earth. This 8th grade level analysis leaves very little room for the greenhouse effect, which, if it even exists, is completely and utterly dominated by water vapor.

Also, your (Coby) 2nd law answer is insufficient. The argument goes something like: the atmosphere at that level is far colder than the surface. How can a colder part of the atmosphere warm the hotter surface up, and still be consistent with thermodynamics? In fact, the 'greenhouse effect' is not at all supported by any primary scientific literature. By that I mean papers. Textbooks and pamphlets and the IPCC reports (secondary and tertiary sources) include explanations and such, but as far as I know there is no rigorous analysis based strictly on the known laws of thermodynamics and physics. I'd love to be proven wrong in this regard, so feel free to point me to a primary source in the scientific literature.

Posted by: Informed | March 11, 2009 12:42 AM

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Informed:

"Temperature increases with pressure. That's why Venus is so hot."

Sorry, you have some serious misconceptions here. It is true that increasing pressure will raise temperature, but a body will not maintain a high temperature simply by being under a constant high pressure. If it worked the way you said, then shouldn't the deep ocean (very high pressure) be hotter than the surface waters (low pressure)? Also, the pressures at the bottom of the ocean are greater than at the surface of Venus, so why 1oC here and 400oC there?

Do you think a canister of high pressure O2 drifting in space will remain hot forever just because it is high pressure?

You clearly have something very wrong in your reasoning.

"as far as I know there is no rigorous analysis based strictly on the known laws of thermodynamics and physics."

I'm sorry if I sound harsh, but as far as you know is really not very far. I would like to recommend Spencer Weart's excellent History of Global Warming for relevant research dating back a hundred years that should answer your questions, if they are sincere.

Posted by: coby | March 11, 2009 10:15 PM

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Coby:

No of course the ocean will not be warmer at the bottom: it is not a gas. PV = nRT is the ideal gas law. It in no way describes or is related to liquids. I should think that this would be fairly obvious.

And of course the high pressure O2 in space will eventually cool... The ideal gas law isn't perfect. It's a good approximation that gets across the form of the relationship. It deals with ideal gases, which have perfectly elastic collisions with one another and the walls of their container, this is of course never the case. There will be heat loss due to collisions with the container walls. Eventually the system will be at thermal equilibrium, with a large part (almost all of it, eventually) of the original thermal energy of the gas transferred to the walls of the canister, which will then radiate that energy away. Nothing you posted makes my statements about pressure being a major factor in the Venusian temperature invalid.

As to the second part of your reply, I appreciate the effort, but I've been over all that stuff many times. Like I said, in the PRIMARY SCIENTIFIC LITERATURE there has been no comprehensive analysis, from a physics standpoint, of the so called atmospheric greenhouse effect. It's postulated a few times, brought up, thrown in to other calculations as if it is already proven, etc, but there is no paper that is dedicated to the issue of explaining, in exact mathematical terms, what exactly it is. Again, even in the first analysis, that 33oC figure is used. All of this difference is assumed to be a direct effect of the greenhouse effect. The simple fact of the pressure that the atmosphere (regardless of its makeup) exerts on the surface, and the temperature increase that nonzero pressure requires, is left out.

Posted by: Informed | March 12, 2009 12:53 AM

47

So you are saying that the ideal gas law is too simple to accurately describe an O2 canister floating in space, but is just fine for an atmosphere on a planet floating in space. Sure, whatever.

Re your "search" for the missing foundation of GH theory, please stop with the bluffing. The IPCC report is completely reference to primary scientific literature. The link I offered you is completely reference to primary scientific literature. Here are a handful of the over 2000 at the History of Global Warming site:

Tyndall, John (1861). "On the Absorption and Radiation of Heat by Gases and Vapours..." Philosophical Magazine ser. 4, 22: 169-94, 273-85.

Tyndall, John (1873). "Further Researches on the Absorption and Radiation of Heat by Gaseous Matter (1862)." In Contributions to Molecular Physics in the Domain of Radiant Heat pp. 69-121. New York: Appleton.

Arrhenius, Svante (1896). "On the Influence of Carbonic Acid in the Air Upon the Temperature of the Ground." Philosophical Magazine 41: 237-76.

Wood, R.W. (1909). "Note on Theory of the Greenhouse." Philosophical Magazine ser. 6 Vol. 17: 319-20.

Lee, R. (1973). "The 'Greenhouse' Effect." J. Applied Meteorology 12: 556-57.

Here is that bibliography organized by calendar year.

Posted by: coby | March 12, 2009 9:18 AM

48

If the greenhouse gas effect exists where is the test data that shows the effect of variations in concentration and the curves for the temperature changes vs concentration? Why hasn't someone done an experiment that uses 100% CO2 or methane and developed prove that the greenhouse gas effect exists? I only see retoric no test data.

Posted by: cleanwater | May 12, 2009 3:01 PM

49

Hi cleanwater,

Where have you looked? You could start with the comment directly above your own.

Denying the greenhouse effect is denying radiative physics is denying whole swaths of standard first year textbook science in numerous fields.

Posted by: coby | May 12, 2009 3:26 PM

50

Coby: I have check Arrhenius and R.W. Wood and found that Arrhenius is all theoretical numbers no actual experimental data. The work of R.W. Wood is based on experimental work and he proves that the greenhouse gas effect does not exist. I am trying to get copies of Tyndall and Lee but keep going in circle on the internet. How about some real experimental data showing your case not just rhetoric or computer models based on fortune telling.

Posted by: cleanwater | May 13, 2009 2:59 PM

51

Cleanwater, he already addressed that. It isn't the most comprehensive approach I've seen, but it makes up for it with readability.

If you dispute the basis of the greenhouse effect (hint: If you can't find Tyndall's paper online, get to a university library), you can perform some basic experiments yourself, such as this one (which you can also repeat with different gases). The results you'll get will show the well-established logarithmic relationship between concentration and radiative forcing. As Coby notes, if you deny the greenhouse effect, there's a lot of other physics you'll end up denying, up to and including basic thermodynamics (explain why the Earth's night temperature is warmer than its blackbody temperature, for instance).

Note that mapping net forcing (i.e. the total forcing from natural and anthropogenic sources) to exact temperature change on a planetary scale by observational measures cannot be done without the use of a model, unless you happen to have a spare Earth or two and a time machine (which itself would be a model, by the way). We can use paleoclimate records to predict ranges experimentally, but really that's beside the point -- if the net forcing is nonzero, there will be a change in energy balance and thus a change in climate.

Posted by: Brian D | May 13, 2009 3:10 PM

52


http://www.theinternetpetvet.com
Attention Brian D. and Coby: Review of Model Experiment about the Greenhouse Effect. After studying the experiment above I have the following questions and comment.
1. Are the two containers the same size, shape and type of glass? Different types of glass absorb different wave lengths of IR and heat up differently.
2. Where are the thermometers located relative to the light? Are they in the light path were they would absorb some of the IR thus skewing the data.
3. If the greenhouse gas effect exists there should be a different temperature of the black cardboard in the CO2 container. The temperature was not measured therefore this experiment only illustrates that the CO2 heats up. Does it heat from absorption or from conduction of different heating of the container?
4. Was the experiment done with other “greenhouse gases?”as CH4 butane, natural cooking gas, Nitrogen trifloride ?
5. Did the experimenters reverse the gases to the other container to evaluate differences in the set-up.?
6. Was more than one set of test done? Is there more data to evaluate?
7. Did you monitor the temperature of the water in the trays? If the trays are in contact with the gases there is conduction of heat from the bottom of the glass trays to the gases.
8. I can not be sure from the photos but it appears that the top of C1 container is closed ,if this is true then you have created a confined space heating container (greenhouse effect). It has been proved by R.W. Wood and others that the heating in a greenhouse is caused by the restriction of heat convection and not back radiation of IR. The top of C2 appears open thus keeping the temperature lower by convection. Good job of cheating..
9. What you have shown is what has been known from IR spectroscopes that different gases absorb different wave lengths of IR.
10. I have done a similar experiment except I used clear Mylar balloons( very little or no absorption of IR as opposed to glass) Based on IR thermometer reading and available data on IR absorption by glass much of the heating in the experiment was from the glass. This was not measured in the experiment. By using Mylar balloons in bright sunlight there was no heating of the gases inside 4 balloons above ambient temperature(measured with an IR thermometer reading to O.1 degrees F. The contents were 100% CO2, 100% butane, natural gas (CH4 and CO2) and air. The black cardboard I used did not show any differential heating between areas in the “shadow” of the balloons compared to “un-shadowed” areas –no back radiation from the “greenhouse gas effect” The black cardboard did increase in temperature from ambient of 95 degree F to 175 degree F. uniformly across the surface.
11. If the greenhouse gas effect exist why hasn’t it been applied to something useful like thermopane window filled with a “greenhouse gas” that would back radiate IR into the house and create insulated windows with R=30 values.
You ask the question “Why can it be warmer at night than during the day? Any elementary school student that can read a weather report know that daily temperature are effected by hot or cold air masses moving across the area. It is also obvious that
on a clear night the temperature will cool down much faster that on a cloudy night. Water is not a greenhouse gas in spite of what many people say- it has known properties that explain temperature differences 24/7/365. There is no back radiation –there is reflection of light or blockage of light(clouds) energy release as lightening and other thermo effects that are within the Laws of physics and thermodynamic.
When you find reliable experimental data that proves that the “greenhouse gas effect exists please share it with the world.
In the mean time read “Falsification of the Atmospheric CO2 greenhouse effects within the frame of Physics” by Gerhard Gerlich and Ralf D. Tscheuschner and when you understand it in five or ten year( a PhD level –way above your level of intelligence) and the global temperature has dropped by the 0.6 degrees that it has gone up over the passed 120year you will realize that man-made global warming is a hoax.

Posted by: cleanwater | May 14, 2009 3:09 PM

53

Brian D.
Let us suppose the results of the experiment you propose are indeed correct and accurate.

The vessels are 0.037% CO2 and 100% CO2.
And we see a 6degC difference.

What does this say about two vessels whose content are 0.037% and say, 0.080%, or 0.100%?

I think you may have solved this whole quandry for us?

Posted by: Paul in MI | May 15, 2009 6:17 AM

54

cleanwater -

You have some good questions in that post (along with some inane questions). You should perform the experiment yourself so you can address them.

If Gerlich and Tscheuschner is so advanced, and hard to understand, how can you be sure they didn't make any errors? Or are you just so smackin' smarter than the rest of us, that you know it's correct?


Paul in MI -

I think you may have solved this whole quandry for us?

The only thing this experiment shows is the fact that CO2 is a greenhouse gas. It does not intend to show/predict/whatever the relationship between CO2 and temperature on a global scale, and to suggest otherwise is just asinine. If you're a skeptic, fine, but you're just grasping at straws here.

Posted by: Adam | May 15, 2009 7:16 AM

55

Adam,

We should draw "no" inference from a >2000x increase in concentration of CO2 causes a 6 degree C rise in temp? In a closed box?

Would one not even be curious as to what a 2 or 3 times increase in concentration would do? In a closed box, or in open space?

Posted by: Paul in MI | May 15, 2009 10:11 AM

56

Comments of Greenhouse gas effect 5-16-09
Gentlemen: I will try to answer all the comments as many of them are worth sharing what I do know and give references where someone else does a better job of explaining why the greenhouse gas effect does not exist.
A general comment on the supposed test “proving that the greenhouse gas effect exists.” This is a very poorly set up experiment. Every one of my question or comments was meant to point out an error or fault with the experiment. Having done a bite of experimenting for my Masters degree and having had my butt reamed for poor definition of the problem and ways to set up the experiment to either prove or disprove the hypotheses behind the experiment. I can recognize other’s mistakes. The experiment of proving that the “greenhouse gas effect exist” must show that there is “back radiation “caused by properties of CO2 and other gas molecules. It has been shown by Niels Bohr in 1922 that when a gas molecule absorbs electromagnetic energy as photons from IR it causes the electrons to go to a higher energy shell in the molecule- it does not cause the gas to heat up. The individual molecule can only absorb a specific amount of energy before it is reradiated as “light energy” with the same wavelength as was absorbed. The “light energy” will be radiated in any direction ( a three dimensional model) there is no force that cause it to go back in the direction that it came from. Using
the picture used by advocates of the Greenhouse gas effect is pure fantasy. There no fixed layer of CO2, in the troposphere –The CO2 is distribute through out the troposphere thus if the molecule (very few-380ppm) absorbs the specific wave lengths that it will accept (only 2 or 3 wave lengths in the IR range) they can be from any direction thus during the day sunlight will be the primary source –very little from outward radiation from the heated Earth. At night after sundown the IR radiation from Earth could be absorbed by the CO2 however as stated above only 2 or 3 wavelengths of the IR spectrum will be absorbed. Any particular molecule may or may not absorb the IR depending on its individual energy level, because most of the molecules are already at an excited level from the sun, most of the IR from Earth will escape into space.( about 1 millionth of out bound IR will be absorbed then reradiated in any direction). This is proved every day because the temperature from one day to the next is totally different. Daily temperatures are obviously controlled by moving air masses. Ask any weatherman-meteorologist-The best they can do is predict the next 5 days with some reliability –why do you believe a Climatologist who is trying to use his frosty crystal ball to predict 10-20-30- 50- 100 years into the future. They tell us that they have this great computer model that makes all kind of assumptions but because there are limitations in the capacity of the computers they have to ignore the effects of water and sun light variation. As with all computers “garbage in is garbage out” Having checked with many Meteorologists ( and a few climatologist including the retired head of the Climatologist Society) that work with the data daily they know that the greenhouse gas effect is bull and that Man-made global warming is the product of corrupt politicians. If the politician and wacky environmentalists would close their mouths the Earth temperature would drop at least 5 degrees.
Just a short comment about “heating” and “Heat transfer” –Thermodynamics-this is very simplified so the wacky environmental can understand it- gases do not get heated by absorption of radiation they get heated from conduction from other heated bodies- and when it heats up it causes the molecules to move faster( higher energy) this energy will then transfer to other molecules by collisions. Like pole balls colliding. This explains why the experiment that was supposed to prove that the greenhouse gas effect exists is in error. The light passes through the gas without heating it (Per Niels Bohr and others) then it is absorbed by the glass containers and the black cardboard inside the containers that heat up and then the gases are heated by conduction. The reason I was concerned whether one of the containers with the air was open is that convection through an open top would prevent heating as much as the closed top container with CO2 (greenhouse effect) We all know that the greenhouse effect exists. The problem is the explanations of why it happen is not understood- Look up the work of R.W. Wood that explains what happens –not back radiation of IR.
The above is an answer to Brian D and Paul in Mi
To Paul in MI –you did not read the previous comments of early May- I have performed similar experiments that were better thought out and the results were totally different. That is why I have gone into the above dissertation on basic physics, thermodynamics, not so basic radiation physics and a little nuclear physics.
To Adam –the experiment does not prove that CO2 is a greenhouse gas- it proves that the greenhouse gas effect does not exist- again it proves that they set the experiment up wrong and proved the opposite –the greenhouse gas effect does not exist.
To Paul in Mi- You are very good to question the reference to “Gerlich and Tscheuschner “ this is a first class reference because I have done the tests that they explained and gotten the results they said I would . Yes it is written by Ph D physicists for knowledgeable scientists. It may have some error but reading the comment there have not been any that shows any errors just rhetoric by environmental wachos who do not want to realize the works of Fourier, Tyndall and Arrhenius is Hypothesis that contain theoretical calculations and no actual test data. There has been much scientific research and great scientific discovery like the work of Einstein, Niels Bohr and many others that shows that these early Hypotheses have not been supported by facts.
Another reference that I have given before is “Greenhouse Gas Hypothesis Violates Fundamentals of Physics” by Dipl-Ing Heinz Thieme This work has about 10 or 12 link that support the truth that the greenhouse gas effect is a hoax. It is a lot easier for the average person to read and understand. It also is consistent to the work of Gerlich etc.
Another reference is “Ponder the Maunder” that is an excellent reading for the beginner.

Adam-do you think “I am grapping at straws? In additions I have communicated to physicists that are experts in IR photography and they have supplied data on the absorption of IR by CO2 and other gases. This supports the fact that the greenhouse gas effect is a hoax.
I am not contending that what I have written is absolutely correct, much has been simplified for understanding. Many of the references and there links give more complete explanations. It is not possible to condense 7000 years of scientific research and learning into a few pages. There have been many mistakes made during that time like the Earth is Flat (Known by the ancient Egyptians that it is spherical) or that the Earth is the center of the Universe but to go back 150 years to a Hypotheses that has not been proven by data is asinine.
There have been references to the 95% CO2 atmophere of Venus and the fact that it is at a mush higher presure than on Earth and the temperature of it is mush higher. Some idiots claim this is proof that the greenhouse gas effect exists-they are wrong.One Venus is much closer to the Sun therefore it recieves much more radiation than Earth and this will make it hotter. Because of the higher pressure and higher concentration of CO2 there are many,many,many more molecules of CO2 in the atmosphere-if the greenhouse gas effect existed all the IR radiation from the hot Planet (2 or 3 wavelenghts) would be capured and back radiated to the planet.NASA has data that this is not happening.Also there are clouds of Sulfuric Acid over the layer of CO2 that has the same effect as the water cloud on Earth. These are not greenhouse gases-Water has proven effects on temperature because of known properties. There are Thousands of volumes about water and it effect. Water and CO2 are essential for live on this planet.

There are a few million pages of scientific information or more and yet people prefer to believe the fantasy and fiction of a few corrupt politicians, Henny Pennies and climatologist that use frosty and dirty crystal balls to predict 50 or 100 years into the future based on illogical and unproven fantasy.


Posted by: cleanwater | May 16, 2009 1:06 PM

57

cleanwater,
I think you mis read the top of Adam's post as being from me.
He was referring to me in the middle of his post. My only comment was if Brian is correct, what do the results of the test say about really trivial amounts of CO2, as opposed to 100%.

Posted by: Paul in MI | May 16, 2009 1:35 PM

58

Paul in Mi: sorry for misreadingthecomment. If I understand your question the answer would be that as the atmosphere on Venus is near 100 % at 95% and the greenhouse gas effect does not effect the temperature-per tests by NASA information. Thus If the experiment at the University of Bremen had been performed properly At 100% CO2 or CH4 Or any other Supposed greenhouse gas the temperature would not have increased. The experiment I performed with mylar balloons and 100% CO2,100% butane, natural gas and Air exposed to Sunlight on a bright sunny day the temperature of the ballons did not increase. The gases stayed at the same temperature as the outside air. The blackcard that was placed about 3" away heated up to 145 degrees F. Another test with the same balloons in front of an aluminum painted door-The door heated up to 135 degrees and the balloons were at ambient(93 degrees F). Does this answer your question? Thanks for asking.

Posted by: cleanwater | May 16, 2009 11:07 PM

59

Yes. But not looking for an answer as much as a thoughtful comment. One comment might be> if we increase the GHG by x 2000 and see a 6C increase we may expect something less if we increase it by x 2 or x 3. And how would this help us understand our situation on earth?

Posted by: Paul in MI | May 17, 2009 5:54 AM

60

re comment 56 from cleanwater,

I have to say I have not read such a remarkable mix of ignorance, hubris and plain bull crap in quite a long time. It is much too long to waste time answering every point, but I would like to point out that your level of knowledge is clearly no deeper than the cartoons drawn to show a lay audience the very general principles. Arguing against the specifics of these cartoons is frankly laughable.

Getting scolded by your thesis advisers for not knowing how to set up an experiment hardly seems a ringing endorsement for your skills in that area now, but did they also scold you for talking about things before doing even the most basic research? For example, you do not even know that CO2 is almost completely transparent to direct sunlight and you think predicting climate is like a 30 year weather prediction.

Do some basic research, then you might have an opinion worth listening to.

Posted by: coby | May 17, 2009 4:32 PM

61

Paul in Mi: The comment is very simple- At 3000X the concentration of CO2 would be 11.4% the temperature increase caused by any "greenhouse gas effect" is zero. Thus at 2 or 3 times the increase is still zero. The 6 degree shown in the test is caused by a bad experiment that does not measure what it claims to be measuring. I'll bet this experiment will be pulled shortly because it is so full of errors.

Cogy: Thank you for the endorsement and acknowledgement that you are not knowledgement enough to answer any points in the dissertation. Thank you for telling the world that the dissertation is fact and you cannot present anything to show it is wrong. You obviously do not know how to read- my statement is that CO2 only absorbs IR at 2or 3 wavelengths -thus you are in agreement with me that CO2 is nearly transparent to both visible and IR electromagnetic radiation. Of the total energy delivered from the Sun and the long wave IR being radiated outbound from Earth only about 0.0000001% is available for absorption.
The cartoon is laughable because it is being used by clowns.
To attach the messenger instead of the message is the voice of a loser.

Posted by: cleanwater | May 17, 2009 8:48 PM

62

Contact your Congressman ASAP
Tell your Congressman to get evidence that the Greenhousegas effect exists.
The congress is planning to pass a Cap& steal or Carbon tax tell them that they must get evidence that the “greenhouse gas effect exists” If they cannot get this evidence they should not pass this stupid legislation.

If they pass it then we should tell them that we will not vote for any Congressman that vote for this legislation.
Even if you think that this legislation should be passed-demand the evidence that the “greenhouse gas effect exists”

Posted by: cleanwater | May 23, 2009 9:49 PM

63

G'day all,

What a splendid exchange of ideas. I would like to establish something straight up, so no-one need ever be abusive. I am an aging ignoramus. Lets try get this science debate to being polite, that OK, kids? The strident new men are most welcome in these long geological debates (this particular one about ice ages has rambled on in print since 1840), but since Soapy Sam Wilberforce and Bulldog Huxley were allowed in on another issue, things have gone slightly downhill in the manners department. Time to lift the game?

The debate just here seems to swing around roughly 4% of heat radiated from the surface being trapped, give or take whatever, fine. But what if there is a far greater variable effecting heat flows?

The earth's geomagnetic field varies hugely, over all time scales. That field reverses totally at erratic intervals and the effect seems to be quite large when it does so. We have, despite every one of the four? deep Antarctic drill holes targeting the deepest ice, so far not found anything clearly older than the last reversal, at roughly 800,000 bp and we may never do so. But glaciation in the south, from independent marine evidence, is known to have started some 35 million years go. So, where is all the old ice? It gets blow-torched at every reversal, is my wild guess.

Next, to come to the closer time scale. Every major decline in temperature in the last five thousand years, from the historic record, at least in the northern hemisphere, is matched closely by a radical drop in the VADM, the vertical axial dipole moment of the planet, go see Google or Wiki.

Next, to deal with just this century, the sharpest decline in the magnetic field of this planet has been at the Antarctic Peninsula, right where the sharpest warming on the same planet has occurred. The far more most extensive but not quite as sharp rise in temperature in the north has been more or less centred on the new emerging magnetic north pole, located halfway between Lake Baikal and the Arctic Ocean. As the magnetic lines of force in the north are inwardly directed, as the field there strengthens, that has the same effect on the magnetosphere as a decrease in the south. The Van Allen Belts dip lower and in come more highly energetic protons, electrons and helium nuclei from the sun plus all the very high energy extra cosmic rays. When sunspots are aplenty, it gets hot. When they are scarce it gets cold. But that is all severely modulated by the trends in the geomagnetic field at the time. At present and since Roman times, we have the geomagnetic field declining, more or less. And the temperature with it, as the Roman Warm Period is reckoned to have been hotter than the Medieval, and both were hotter than now, see where what was grown.

You want the references? There are none, this is it. Merely some lunatic looking at the time-series maps and the ground and satellite temperature and mag data from the real world and then guessing wildly. But, this has a good chance of being the missing main driver of climate change, as it can explain the ice ages as well as swings now, which ice ages the carbonist model cannot even touch.

Geophysics is not popular with the climate crowd, on both sides of the carbonist argument It has it's own nightmare jargon and it takes a while to get up to speed, like a few years. I am not a geofink, just a geo who uses geofizz, to make it all even less reliable. Any geofink out there care to explain why I am drivelling? Be happy to know.

Try the website above if you want more confusion. And ABC Pool Climate change debating group (of one), for some of the maps, at http://www.pool.org.au/group/climate_change

Hooroo,

Peter.

Closeburn, Queensland, Oz

Pete's Dictum. In science, it's often not either or, reality may be a mix of all four.

Posted by: Peter Ravenscroft | July 14, 2009 4:15 AM

64

Peter Ravenscroft: Hello Peter you may be absolutely correct. The point I've been making is that CO2 and all the other supposed GHG's can not cause global warming. The ghg effect is a Fairly-tale. Based on some other information that may meld with your info is that the Sun is going into a "Solar Hibernation" which will result in significant global cooling.

Posted by: cleanwater | July 27, 2009 1:25 PM

65

"The greenhouse effect is a myth because it violates the second law of thermodynamics!"

Rubbish. That is obvious nonsense. The solar energy gradient drives the whole process, and anyone with the slightest understanding of thermodynamics - or even a person who dropped out of the class after the third week - knows this.

Posted by: B. Troglodyte | August 16, 2009 5:25 PM

66

It is my understanding that the transmission absorption of gasses like carbon-dioxide is primarily the result of molecular resonances with each absorption wavelength corresponding to a mode that that particular molecule may be made to 'jiggle.' Some have suggested that thus excited molecules can only drop down to lesser energy states by re-emitting similar photons. However I also believe that this energy can be exchanged by interacting with surrounding molecules. This is usually called heat conduction.

I find very believable and reasonable the concept put forth by skeptics that the greenhouse effect is subject to a saturation limit or a law of diminishing effect, once the concentration of a greenhouse gas goes beyond the point where more than half of the absorption-wavelength photons emitted from the earth's surface fail to make it to outer space. It is claimed that we are well beyond that point with respect to carbon-dioxide. In simple terms, once a given piano string is cut, it does not matter how many more times it is cut, only that note cannot be played.

As ocean-warming forces dissolved carbon-dioxide out of solution (just like the bubbles you see on the inside of a glass of warming water), I think that past indications high concentrations of carbon-dioxide in the atmosphere are more likely to have been induced by ocean-warming rather than its primary cause.

This does not preclude the fact that man-made industrial pollution may be increasing the greenhouse effect because each new exotic man-made molecule that we add to the atmosphere will have a new set of unique absorption wavelengths. I do question the focus on carbon-dioxide as the primary culprit.

Posted by: Spector | September 11, 2009 11:56 AM

67

Spector,

Wouldn't the amount of energy needed to saturate the CO2 be determined by the amount of CO2 in the atmosphere?

The physics of the greenhouse effect is quite straightforward as compared to the physics of the climate as a whole. It is also easier to measure, for example, by measuring the spectrum of infrared that escapes to satellites in space and seeing how much each gas traps, or by doing lab experiments with containers of CO2, or measuring infrared radiation from the sky at various wavelengths. The more serious of denial scientists (e.g. Lindzhen, Spencer) don't dispute that additional CO2 will cause additional warming; instead they speculate about negative feedbacks in the climate (e.g. a cloud related effect) that will counter the warming. Not that they've found anything to substantiate their ideas or been able to turn them into models with any predictive ability, that would be too much like real science work.

Are you aware of any scientist who has demonstrated (physically) that the ice ages are explainable solely from the small changes in the Earth's orbit without the CO2 feedback contribution?

Posted by: Eric L | September 11, 2009 5:29 PM

68

In this context 'saturate' refers to the increase in greenhouse effect obtained by increasing the CO2 concentration in the atmosphere. Once the CO2 concentration reaches the point where those photons of a particular CO2 absorption wavelength have almost no chance of reaching outer-space from the earth’s surface, I believe a law of diminishing effect for increasing concentrations should set in -- depending on the width and shape of that absorption band.

If you have camera filters that only block green light, using three such filters in tandem will not also block red and blue light. It is my understanding that there we already have more than enough CO2 in the atmosphere for 100% absorption at the critical wavelengths. Pure carbon-dioxide is nominally a transparent gas.

Even if the carbon-dioxide greenhouse effect is fully saturated, I believe it is still possible that we may have an increasing greenhouse effect from continued industrial pollution due to other gasses that are being added to the atmosphere.

Posted by: Spector | September 12, 2009 2:00 AM

69

Okay, I thought by saturation you meant some other claim I've heard.

Yes, the effect is diminishing, but how it diminishes matters. Also, diminishing does not mean there is a ceiling to how much of an effect it can have. So here's the conventional view on how it diminishes:

http://globalwarmingart.com/wiki/File:Atmospheric_Transmission_png

It should be noted that while some bands are saturated (i.e. 100% of radiation in that band is absorbed), that does not imply that further increases in greenhouse gas concentration have no effect on that band. Rather additional greenhouse gases will cause the radiation to be captured closer to the Earth's surface which still increases warming. However rather than doubling as concentrations double, the overall effect proceeds only by small increments giving rise to a logarithmic progression rather than a linear one.

So when you get to the point of diminishing returns, doubling the amount of CO2 still increases temperature, and doubling again increases it that much more, and so on -- twice as much CO2 required to get the same effect on climate, but you can always get that much more effect if you raise CO2 enough. And of course, not every band is saturated, especially at the edges of the bands.

So your intuition is in a certain qualitative sense correct. But do you have any reason to believe that the various climate scientists working on this have not correctly understood the physics or measured the atmospheric scattering and absorption?

Posted by: Eric L | September 12, 2009 3:04 PM

70
It is my understanding that there we already have more than enough CO2 in the atmosphere for 100% absorption at the critical wavelengths.
This is absolutely wrong. It was proposed early last century and disproved by physicists back in the 1950s.

Here's an explanation of the real science.

The greenhouse mechanism doesn't work like stacking photographic filters (and since this analogy, along with the saturation argument, are standard denialist claims, I'm sure you've been misled by a site designed to *mislead* you).

Posted by: dhogaza | September 12, 2009 5:03 PM

71

I find that real data on CO2 absorption appears to be very hard to find as open source data on the web. Access to HITRAN data is restricted. The Wikipedia article on carbon-dioxide does not appear to include any actual data on this critical topic. I have found plots that do seem to indicate a law of diminishing effect (soft saturation) setting in around 50 ppm. It would appear our current CO2 level is about 387 ppm, up only 107 ppm from the pre-industrial level of 280 ppm.

The reference provided by dhogaza seems to support my conclusion. One plot (in part II) shows that a 400% increase in CO2 concentration would cause only a slight increase of the width of the saturation band. To date, we have only seen a 38% CO2 concentration increase above pre-industrial levels. As radiated thermal energy is proportional to the fourth power of absolute temperature, it should take only a minor temperature increase to compensate for this minimal reduction in the width of the transmission window.

I still believe that the carbon-dioxide greenhouse effect is self-limiting and does not yet present a clear and present danger of climate-change catastrophe.

Posted by: Spector | September 17, 2009 4:13 AM

72

As radiated thermal energy is proportional to the fourth power of absolute temperature, it should take only a minor temperature increase to compensate for this minimal reduction in the width of the transmission window.

So then a 4% increase in radiated thermal energy would be needed to go with a 1% increase in temperature. You need to keep in mind that a 1% change in temperature would actually be a pretty big change -- about 3 degrees Celcius or 5.5 degrees Farenheit. That's already well into the range of IPCC projections for 2100. In fact, the predicted direct effect of CO2 for 2100 under business as usual scenarios is less than that, a lot of the temperature increase comes from feedback effects like increased H2O greenhouse effect and less snow/ice cover.

Once again, you are correct that the effect is diminishing, it is your assumption that the climate science community is unaware of this and not accounting for it in their calculations that is unfounded.

Posted by: Eric L | September 17, 2009 11:51 AM

73


It appears to me that the public has been repeatedly told that 'Global Warming' is directly proportional to the carbon-dioxide concentration in the atmosphere. When expert climate-science skeptics pointed out that this cannot be true, I found my confidence in the 'accepted' climate-change theory greatly undermined. I am now lead to believe that the public case against carbon-dioxide may be overstated and perhaps, coincidental.

I do not purport to know who is aware or unaware of the diminishing effect of increasing CO2 concentrations. Perhaps this is just one of those distinctions that always get lost in translation.

Posted by: Spector | September 18, 2009 8:56 AM

74
It appears to me that the public has been repeatedly told that 'Global Warming' is directly proportional to the carbon-dioxide concentration in the atmosphere.
If they've been told this repeatedly by climate scientists and those who listen to what they say, then you'll have no problem coming up with a link to a credible quote, will you?

Of course, climate scientists have never said any such thing, which means you're builiding a strawman ...

When expert climate-science skeptics pointed out that this cannot be true, I found my confidence in the 'accepted' climate-change theory greatly undermined.
For so-called "expert" climate-science skeptics to knock down.
I am now lead to believe that the public case against carbon-dioxide may be overstated and perhaps, coincidental.
And, of course, just maybe you're making shit up.

I'm eager to see those references asked for above ...

Posted by: dhogaza | September 18, 2009 5:55 PM

75
It appears to me that the public has been repeatedly told that 'Global Warming' is directly proportional to the carbon-dioxide concentration in the atmosphere
Here's why I think you're making shit up.

Climate scientists have known for about 50 years that long-term forcing due to increased CO2 goes up proportional to the LOG of the increase, not directly proportional.

This isn't something pointed out by "expert climate skeptics", it's something they've read in the basic science, just like every climate scientist alive today and any layperson who bothers to spend an hour or so learning the basics.

You don't understand the basic science if you claim that science states that the relationship is "directly proportional". Rather than undermine your confidence in science, what should be undermined is your faith that you *understand* the science. Because clearly you don't.

As I said above, I'm eager to see a reference to this "directly proportional" claim from a credible source, which will prove to us that you're not just making shit up.

I do not purport to know who is aware or unaware of the diminishing effect of increasing CO2 concentrations
But you led by claiming it was "expert climate skeptics" that discovered this and pointed out, which is equally a (false) claim that mainstream climate scientists (physicists, really, back in the 1950s) who are unaware of the log relationship.

Posted by: dhogaza | September 18, 2009 6:05 PM

76

dhogaza forgets the inconvenient truth that Al Gore made that "linear relationship" famous. Of course, now the casual observer should know it's not true and oh yeah, temp led CO2, not quite the way it was portrayed in the crockumentary. That's where masses of people get incorrect ideas, mass propaganda...

Posted by: PaulinMI | September 19, 2009 3:43 AM

77

PaulinMI,

You are mixing up "linear relationship" with "correlation". Goggle is you friend.

Meanwhile, Spector will likewise fail to come up with anyone knowledgeable claiming a linear relationship between CO2 concentrations and its effect on temperatures.

Posted by: coby | September 19, 2009 6:29 AM

78


I must assume that any scientist who has made serious study of this topic is aware of the log relationship.

From personal experience, I believe that the unlimited direct proportionality of the carbon-dioxide greenhouse effect is a common misconception of the public at large. Perhaps this begins as a simple sin of omission in the press.

I have not, as dhogaza seems to presume, claimed the log relationship to be a recent discovery of climate-change skeptics. I have only said that they have undermined my acceptance of the carbon-dioxide as a possible cause of catastrophic global warming with this information.

Posted by: Spector | September 19, 2009 9:43 AM

79
I have only said that they have undermined my acceptance of the carbon-dioxide as a possible cause of catastrophic global warming with this information.
So let's dissect your logic:

1. Climate scientists have known since the 1950s that forcing isn't linear in the increase of CO2.

2. You, for whatever reason, didn't know this.

3. You learned this from some random climate skeptic site.

$. Therefore you think climate scientists are wrong.

Is it safe to assume that if, by chance, you first learned this from, say, Real Climate, that you would now conclude that the denialists are wrong?

In either case, your conclusion is based on your own prior ignorance, not science (or denialism). At the risk of offending you - this is really stupid.

Posted by: dhogaza | September 19, 2009 12:14 PM

80

Spector was stating what he believed to be common knowledge among the public. And I am not mixing up correlation and linear relationship. That was due to the likes of Al Gore.
Not a denialist.
AGW "informers" need to be more careful in how the message is presented. You may not like the situation, but there it is.

Posted by: PaulinMI | September 19, 2009 1:22 PM

81
Spector was stating what he believed to be common knowledge among the public.
Yes, he's stating that he and some members of the public are misinformed.

Therefore climate science is wrong.

And you agree, apparently.

Posted by: dhogaza | September 19, 2009 1:41 PM

82

"And I am not mixing up correlation and linear relationship. That was due to the likes of Al Gore."

Great. Here's a transcript of the movie:

http://forumpolitics.com/blogs/2007/03/17/an-inconvient-truth-transcript/

I'm sure you'll have no problem showing us where he says there's a *linear relationship", rather than making the less precise point that there's a correlation.

Direct quote, please.

Posted by: dhogaza | September 19, 2009 1:49 PM

83

Spector nor I said climate science is wrong.

We're talking about perception here.

So, again, AGW "informers" need to be more careful in how the message is presented. You may not like the situation, but there it is.

Posted by: PaulinMI | September 19, 2009 4:08 PM

84

"Spector nor I said climate science is wrong"

Spector saith:

I am now lead to believe that the public case against carbon-dioxide may be overstated and perhaps, coincidental.

Shorter form: Climate science is wrong.

Posted by: dhogaza | September 19, 2009 4:34 PM

85


Slightly longer form: 'Some long-term conclusions of climate scientists may be invalid as our understanding of this science is as yet incomplete.' The same can be said of any other living science.

See "CBC Global Warming Doomsday Called Off" on video-google. (44 min)

Posted by: Spector | September 19, 2009 7:17 PM

86

Spector, please have the courage and integrity to own up to what you are saying. You have clearly stated that you think CO2 may not be causing global warming. This is not some "long term conclusion" or incompleteness. This is a fundamental concept of planetary atmospheres and derives from very basic physics.

dhogaza's clarification of your POV and how you say you arrived there is precisely what you have yourself presented.

Posted by: coby | September 20, 2009 6:00 AM

87

Hey, does this MO sound familiar?

The swine flu pandemic could kill millions and cause anarchy in the world's poorest nations unless £900m can be raised from rich countries to pay for vaccines and antiviral medicines, says a UN report leaked to the Observer.

It paints a disastrous picture for the world's most vulnerable people unless there is immediate action. "There is a window in which it will be possible to help poor countries get as ready as they can for H1N1 and that window is closing rapidly," it says.

Posted by: PaulinMI | September 20, 2009 2:09 PM

88

Coby

What I said was that I thought *increasing* carbon-dioxide concentrations should be subject to a (self-limiting) law of diminishing effect on the Earth’s temperature. A logarithmic relationship is just such a law. This appears to be well known by those who should know, but the general public appears to be largely unaware of this technical distinction.

Posted by: Spector | September 20, 2009 2:39 PM

89

A few more points on this:

1. A log relationship and a linear relationship aren't that different when you've only changed the input by 40% so far. This is a rather technical point and not a major omission, particularly in any article not in-depth enough to give a mathematical relationship between CO2 and temperature.

2. It is important to distinguish between the (log) relationship between warming and CO2 and the rate of warming over time. Growth in atmospheric CO2 concentrations has not been linear, it is accelerating due to an increased number of cars and power plants putting it into the atmosphere at an increasing rate. What is usually reported for climate change predictions are business-as-usual predictions of warming over time. These are based on CO2 rise that continues to accelerate, and they generally predict warming will accelerate. This is not in contradiction with warming being diminishing with respect to CO2 levels.

3. You can check here for a fairly recent review of the science and range of predictions. Any predictions assume a log relationship between CO2 levels and temp, as do all projections in the peer reviewed literature. If the news sources you rely on have been suggesting that global warming will be far worse than this report implies, then 1) take that up with them, or switch to news sources more focused on science reporting for this sort of info, 2) don't take that as a reason to dismiss those projections actually justified by the literature, and 3) this will almost certainly not be due to anyone assuming a linear relationship between CO2 and temperature, though I'd be curious to see if you have actual examples.

Posted by: Eric L | September 20, 2009 2:44 PM

90
This appears to be well known by those who should know, but the general public appears to be largely unaware of this technical distinction.

No, this is what you said:

When expert climate-science skeptics pointed out that this cannot be true, I found my confidence in the 'accepted' climate-change theory greatly undermined.

Difficult thing about online discussions is that you can't lie your way out of your previous statements.

Posted by: dhogaza | September 20, 2009 4:05 PM

91
Hey, does this MO sound familiar?

Universally anti-science, are you?

No one will be surprised.

Posted by: dhogaza | September 20, 2009 4:11 PM

92

Universally concerned with inividual freedoms being usurped for the reason of the year.

Posted by: PaulinMI | September 20, 2009 5:18 PM

93

This debate is interesting as Spectre makes a good point, in that as you increase CO2 it has less warming effect and then dogs arse jumps in boots and all spins it around and calls him a skeptic, then before the dust can settle (suprise, suprise) coby jumps in to save dogs arse. My suspicions that Coby and dogs arse are the same person strengthen by the day.

The funny thing is, is that all the CO2 in the world cannot increase the temp as much as the IPCC claim it will by 2100, what causes this temp rise is of course water vapour. But hey lets not tell the masses about that, lets just tell these morons that as you increase CO2 so will the temp. Dont tell them about saturation or the log relationship with IR absorption either.

So yes spectre we are not given the full picture, in fact they have gone to great lengths to not do so, now ask yourself why?

And yes i know dogs arse, i am a denier and all the rest of the names you wish to call me, this does not bother me one iota.

Posted by: crakar14 | September 20, 2009 9:13 PM

94

In this case I was referring to accepted public understanding as promoted by the popular media. The skeptic videos seem to show science divided on this topic.

Posted by: Spector | September 20, 2009 9:55 PM

95

But science isn't divided on this topic.

As for popular understanding, yeah, I suppose if you quizzed a random sample of the population, they would not be able to tell you that CO2 had a logarithmic effect on temperature. And there are plenty of far less technical points on climate that they would not be aware of as well. Does this mean they have been misinformed? What is usually presented to the public are projections for how climate will change over the next century. I gave you a link to some such projections. They are based on a logarithmic relationship between CO2 and temperature. Are they misinformation?

Posted by: Eric L | September 21, 2009 11:08 AM

96
Universally concerned with inividual freedoms being usurped for the reason of the year.
Nice. Thanks for openly admitting that for you, science and knowledge takes second place to political ideology.

Posted by: dhogaza | September 22, 2009 10:17 AM

97
In this case I was referring to accepted public understanding as promoted by the popular media. The skeptic videos seem to show science divided on this topic.
I don't give a rat's ass what skeptic videos "seem to show".

Provide us SOLID EVIDENCE that science is divided on whether or not CO2 forcing increases logarithmically as CO2 concentrations increase.

You're building a strawman, knocking it down, then uses this as a basis to claim that climate science is wrong.

Shorter form: you're lying.

Posted by: dhogaza | September 22, 2009 10:21 AM

98
in that as you increase CO2 it has less warming effect and then dogs arse jumps in boots and all spins it around and calls him a skeptic

Liar. I didn't call him a skeptic.

Posted by: dhogaza | September 22, 2009 10:25 AM

99

freedom is not a political ideology, it's a birthright for all.
how it is maintained is political.

Posted by: PaulinMI | September 22, 2009 1:13 PM

100

but, yes, openly admitting that anything else takes second place to freedom.

Posted by: PaulinMI | September 22, 2009 2:09 PM

101
but, yes, openly admitting that anything else takes second place to freedom.

Your honesty is refreshing. However, ignoring science in the name of freedom isn't going to cause the problem to go away.

Posted by: dhogaza | September 22, 2009 3:21 PM

102

dhogaza, the dialogue is appreciated.

I would claim freedom is the foundation for solving the problem.

Posted by: PaulinMI | September 22, 2009 5:30 PM

103

Thanks for the criticism. In view of the fact that solar activity over the past two years has dropped to the lowest levels in more than 150 years and shows no real sign of recovery, I propose to hold my own opinion in suspension for the next two or three years.

In that period, a continuing increase of global temperatures with this greatly reduced solar activity would fully discredit the solar-driven climate hypothesis proposed by skeptics.

On the other hand, I believe the commencement of a *solid* cooling trend in the face of increasing CO2 in the atmosphere would indicate that the current theory needs to be restudied.

Posted by: Spector | September 22, 2009 6:51 PM

104

PaulinMI,

Don't forget puppy dogs and apple pie. All together, that should fix everything.

Posted by: coby | September 22, 2009 8:50 PM

105
I would claim freedom is the foundation for solving the problem.
Which, of course, includes the freedom to take collective action.

People like you want deny that freedom for those of us who want to take advantage of it...

Collectivism isn't anti-freedom when people insist on acting collectively.

Of course, you'll say "collectivism is anti-freedom when people agree on limiting behavior, like random murder and rape and stuff! People should be *FREE* after all!"

And next you'll accuse me of using ridiculous examples which are false because they involve people, not corporations ...

Posted by: dhogaza | September 22, 2009 9:18 PM

106
In that period, a continuing increase of global temperatures with this greatly reduced solar activity would fully discredit the solar-driven climate hypothesis proposed by skeptics.
Actually, even holding steady in the face of reduced solar activity discredits the "it's the sun!"" people.

We have about 50 years of good data regarding solar output and global warming, and, as Lindzen (the best scientist on the skeptic side) says, "it's not the sun!"

Posted by: dhogaza | September 22, 2009 9:21 PM

107
On the other hand, I believe the commencement of a *solid* cooling trend in the face of increasing CO2 in the atmosphere would indicate that the current theory needs to be restudied.
So your claim is that basic CO2 physics would require the earth to continue warming even if the sun were to disappear? Go to zero?

You're saying that any reduction in solar insolation will be overwhelmed by CO2 forcing? Even if solar insolation reduces to zero?

Sorry, this is simply stupid.

Posted by: dhogaza | September 22, 2009 9:24 PM

108

Which, of course, includes collective action.
Not sure where corporations and murder fit in.

Posted by: PaulinMI | September 22, 2009 10:05 PM

109

dhogaza
"So your claim is that basic CO2 physics would require the earth to continue warming even if the sun were to disappear?”

I made no such claim -- you did. I do not think you need be afraid that the sun is going to disappear just because we have entered an abnormally long period when sunspots are few and far between.

At the very least, a significant cooling trend would void the 'it's not the sun' argument unless that cooling could be attributed to other causes such as volcanic eruptions.

Posted by: Spector | September 22, 2009 11:39 PM

110

Quick question to all: When was the last time we had a solar minimum combined with a La Nina as we've experienced in the last year? What was the temperature then?

Posted by: Chris S. | September 22, 2009 11:46 PM

111
At the very least, a significant cooling trend would void the 'it's not the sun' argument
Actually the fact that temps have remained high despite the solar minimum would be enough to do that for logical people.

Posted by: dhogaza | September 23, 2009 9:29 AM

112

Chris,

An easy place to look up the solar and temp data is this site:

http://woodfortrees.org/plot/wti/mean:12/normalise/plot/pmod/mean:12/normalise

So 2008 was warmer than 1999, which was also a La Nina year, even though 1999 was during a solar maximum.

Here is some El Nino/La Nina data that goes back before 1999 (oddly it does not come up to today, maybe someone can find a better link):

http://www.atmosphere.mpg.de/enid/2__Major_wind_systems/-_El_Ni_o___SOI_192.html

So 1996 was a La Nina year that happened during a solar minimum, and it was cooler than 1999. 2009 has so far been warmer than 2008, even though solar output has continued dropping, primarily due to it being an El Nino year.

Posted by: Eric L | September 23, 2009 11:06 AM

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