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« Tazarotene (Acne acetylenes) | Main | Solvated Electrons (Blue?!) »

Tiron (And then, the mighty Tiron bound the iron tightly.)

Category: Dyes
Posted on: September 11, 2007 7:34 PM, by Molecule of the Day

Tiron is a metal ligand and can be used in colorimetric metal assays.

# InChI=1/C6H6O8S2.2Na/c7-4-1-3(15(9,10)11)2-5(6(4)8)16(12,13)14;;/h1-2,7-8H,(H,9,10,11)(H,12,13,14);;/q;2*+1/p-2<br />


Transition metal complexes tend to have the happy property of having their frontier orbitals separated by energy characteristic of photons of visible light - that is, they end up having pretty colors. I've never actually used it, but Merck claims complexes with different metals that span essentially the whole visible spectrum - iron gives blue, copper greenish-yellow, titanium orange, and molybdenum yellow.


For another example of a colorimetrically useful metal ligand, see my entry on that wonderfully named staple of undergrad analytical chemistry labs, eriochrome black T.

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Comments

Erio Black T is my absolute favorite indicator ever. (Pretty colors.)

Posted by: psi*psi | September 17, 2007 11:55 PM

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