I have to admit, I am a sucker for common names. Why would you grab a bottle of mercury (II) chloride when you could get some "corrosive sublimate"? 3-methylindole? No thanks, give me skatole (named for its smell!). Methyl tert-butyl...
Read on »
Posted on January 24, 2008 12:47 AM • 4 Comments • 0 TrackBacks
Valencene is a citrus odorant found in the Valencia orange, hence its name:...
Read on »
Posted on November 13, 2007 8:13 PM • 1 Comments • 0 TrackBacks
Previously, I covered ethyl thiolactate, which is one of those oddly sweet smelling thiols (like grapefruit mercaptan). Ethyl lactate also smells nice....
Read on »
Posted on August 24, 2007 6:57 PM • 0 Comments • 0 TrackBacks
Previously, I covered ethyl thiolactate, which is one of those oddly sweet smelling thiols (like grapefruit mercaptan). Ethyl lactate also smells nice....
Read on »
Posted on August 24, 2007 6:57 PM • 2 Comments • 0 TrackBacks
Hmmm, people don't like being told not to leave certain comments. Thanks for the snark and corrections of the chemical formula. I am off banned drug-related entries for a long while again, they're just not worth the hassle, and there's...
Read on »
Posted on July 31, 2007 7:36 PM • 5 Comments • 0 TrackBacks
It is no secret that I enjoy smelly compounds... a lot. Here's a short list of what I seem to have covered at this blog (hits for "stinky" or "smell"). I'm sure I missed some I've already written up. If...
Read on »
Posted on July 12, 2007 7:37 PM • 8 Comments • 0 TrackBacks
Brief entry today, watching more debates... Diacetone alcohol is a common solvent industrially - it is responsible for a substantial portion of the ineffable aroma of Sharpies....
Posted on May 3, 2007 8:40 PM • 1 Comments • 0 TrackBacks
Yesterday, I covered the intense odorant found in popcorn. Today's molecule is another intense odorant, cis-hexen-3-al....
Read on »
Posted on April 11, 2007 9:38 PM • 2 Comments • 0 TrackBacks
Synthesizing big cyclic molecules is hard ("macrocycles") - closing a long chain of carbons into a ring often results in just making polymers and oligomers ("intermolecular" reactions). One early way of closing rings on themselves ("intramolecular" reactions) was to perform the reaction at high dilution. An example is illustrative:
Take an empty swimming pool and fill it 10% of the way up with snakes. Observe how the snakes are much more likely to bump into each other than curl up on themselves. This is analogous to an intermolecular reaction.
Obtain a second swimming pool and fill it 90% of the way with water. Now dump the same number of snakes in. If necessary, you can reuse the snakes from part 1. Observe how the snakes are much less likely to bump into one another, and many will end up touching part of themselves with another part of their body. This is analogous to an intramolecular reaction. As go snakes, so go long chains of carbon.
Read on »
Posted on February 15, 2007 10:00 PM • 4 Comments • 0 TrackBacks
Jasmone is an odorant constituent, of, unsurprisingly, jasmine flowers. It's somewhat unique by virtue of its biosynthetic pathway. Back with a full entry tomorrow....
Posted on February 5, 2007 7:37 PM • 0 Comments • 0 TrackBacks