Paraformaldehyde (From gas to gears)

Formaldehyde's funny stuff. It's naturally a gas. If you put too much of it in solution, it will polymerize and form a polyacetal, "paraformaldehyde," which is just -O-CH2- repeating over and over.

Because of this tendency towards polymerization, formaldehyde of commerce is sold with a little methanol added to keep it in solution. Interestingly, formaldehyde polymer is used as a plastic - and it's food approved! In some ways, it stands to reason - the stuff won't dissolve in much of anything so it's pretty chemically resistant. On the other hand, you can actually "crack" paraformaldehyde just by heating it (releasing formaldehyde gas), which makes it a little scary to think of it being in your kid's Hot Wheels.

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Not only that, but you can accelerate breakdown of the crosslinkage with a few drops of NaOH.

Somehow I can't think about formaldehyde without mentioning Bakelite.

By justawriter (not verified) on 28 Aug 2007 #permalink

It's a lot more scary thinking of it in my food packaging.

By Richard Gay (not verified) on 28 Aug 2007 #permalink

Maybe you could help me understand something.

In our lab we have a variety of different fixatives. Formalin, formaldehyde (with methanol stabilizer), paraformaldehyde etc.

Now, from what I understand they all are essentially formaldehyde and crosslink based on the same mechanism of action, but what, other than absence of methanol or other stabilizers, is the difference between the different fixatives?

I've always just used paraformaldehyde, it works, is easy to make, etc., but is there any difference in their fixative ability?

(CH2O) n, a white powder - The dust may form an explosive mixture with air.

By Mikael Franzen (not verified) on 29 Aug 2007 #permalink

Delrin like Teflon is all about endcapping. With endcaps the polymers are tough as nails. Without endcaps they thermally unzip.

Where I work we use measured amounts of paraformaldehyde in 'fry-daddys' and turn them on to fumigate our labs (of course, I wouldn't recommend this at home without proper air-handling).