Molecules in the news...

A couple previous molecules of the day were in the news today: polylactide and lead chromate.

I previously covered the use of polylactide in plastic bottles. I also covered a big downside - it's not the sturdiest stuff. Today, Popular Science has a story about its use in plastic bags, which isn't that bad an idea strength-wise, but it is a bit of a bad idea in the sense that we need to wake up to the fact that we are running up against a wall in our ability to ability to produce enough corn to produce oil, staggering though our ability to produce it is.

Also, lead chromate, which apparently makes its way into artificial turf as a pigment. As was pointed out in the comments, it's not very soluble at all, but bacteria have a knack for concentrating whatever's around. Apparently, it's starting to show up in the soil under some of this artificial turf. Apparently anywhere from 10 to 500mg/kg is normal for urban soil, so I imagine it's in the 100s of mg/kg elevation. Can there possibly be that much pigment in there? Milligram(s) per square centimeter? I'm not following. Comments especially welcome here...

That's the thing about pigments that are exposed to light - it's tricky to make a UV-fast dye! Metals tend to hold up a little better. White (a very hard effect with organic dyes) is usually achieved via titanium dioxide. We used to use another lead pigment to make white, but we found out kids who eat titanium paint chips grow up healthier than those who eat lead paint chips!

More like this

I swore I posted this yesterday, but there's no sign of it. Thanks to Hillary for prodding me... Titanium isopropoxide is a Lewis acid and useful in organic synthesis for this reason. It's also useful for synthesis of various titanium compounds. Another neat thing about Ti(OIPr)4 is that it…
By Elizabeth Grossman While commercially manufactured polychlorinated biphenyls (PCBs) were banned by the US Environmental Protection Agency (EPA) in 1979 due to concern about their extreme environmental persistence and toxicity – including potential to cause cancer – current EPA regulations allow…
The US FDA has released a statement based on finding from the Texas Department of State Health Services on December 23, 2009: The Texas Department of State Health Services is warning consumers, especially pregnant or breastfeeding women, to avoid consuming a traditional product called "Nzu" because…
Maybe, but you should certainly avoid deli meats for the listeria (If you follow through that link and read you'll know why). This isn't an abstract risk, Listeria out breaks are happening all the time (just ask a Canuck how their year went). Let's not go down that road and get back to the nitrates…

A scientific wrench turns nuts. An Enviro-whiner wrench is nuts turning. "Best efforts will not substitute for knowledge," W. Edwards Deming.

The single outstanding universal attribute of religion is that it does not work. Test of faith!