The subject of the "spin" of the electron comes up again and again, so as pointed out in a comment, I really ought to do a post explaining what it is and how it works. As a bonus, this gives me the opportunity to do the dorkiest thing anyone has ever done with a cute-toddler video, namely this one:

(That's an early version of SteelyKid's new favorite game. I'll put a clip of the final version of the game at the end of this post.)

So, electron spin. Electrons, and all other fundamental particles, have a property known as "spin." This is an intrinsic angular momentum associated with the particles, as if they were little spinning balls of charge. I say "as if" there, because they are not literally spinning balls of charge, because the spin angular momentum associated with fundamental particles has some properties that are very strange, and completely unlike the behavior of spinning basketballs, or gyroscopes, or figure skaters, or whatever your favorite example of a system with angular momentum is.

First, though, how can we say with certainty that these *aren't* literally spinning balls of charge? Well, in addition to their angular momentum, the fundamental particles also have a magnetic moment associated with them, which is to say they behave like tiny little bar magnets with a north and south pole. This is exactly what you would expect for a spinning ball of charge, but if you go through the math, you find that it can't possibly work.

If we want to say that the magnetic moment of the electron is due to the motion of a spinning ball of charge, then we can easily calculate what the spin rate should be, given what we know about the size of an electron. If you use the maximum size you could possibly associate with the electron, the "classical electron radius", and calculate how fast a sphere of that size would need to be spinning to produce the observed magnetic moment, you find that a point on the surface would need to be moving at a speed several times the speed of light in vacuum, which is impossible. That's also a gross overestimate of the size of an electron-- as far as well can tell, the electron has no physical size. It's a point particle, and thus doesn't have a surface that can be physically rotating.

OK, then, maybe the magnetic moment is just one of those things, you know? Maybe the "spin" angular momentum isn't really angular momentum at all. This is also false-- spin angular momentum is real angular momentum. We know this because you can drive transitions from one spin state to another using polarized light, and we know from careful experiments done in 1936 that the angular momentum carried by light is real angular momentum. The angular momentum of a polarized photon can be used to make physical objects rotate, and it can also be used to make electron spins change states; this at least strongly suggests that spin angular momentum is real angular momentum comparable to that of spinning basketballs and all the rest.

The spin angular momentum of an electron does have some strange properties, though, that are very unlike those of ordinary rotating objects. For one thing, it has only two possible states, "spin up" and "spin down."

To understand the meaning of this, we have to back up a moment and talk about classical angular momentum a bit. Angular momentum is a quantity associated with a spinning object, and it has a direction associated with it. The direction of the angular momentum of a spinning object is along the axis of rotation, and determined by the direction of spin. If you look down at a record on a turntable, and it's spinning clockwise, the angular momentum points down, into the turntable. If it's spinning counter-clockwise, the angular momentum points up, out of the turntable toward you.

For a classical object, this angular momentum can point in absolutely any direction, and can be moved around by exerting forces in the appropriate places. When we move to talking about quantum mechanics, which gets its name from the fact that the theory only allows certain discrete states, this picture needs to be "quantized," but the transition from classical to quantum isn't too bad. If you have a moving object in quantum mechanics, and ask what the allowed states of its angular momentum are, you find that they are integer multiples of Planck's constant, up to some maximum value, and down to the same negative integer. That is, if the system you're looking at can have up to 3 units of angular momentum, the states you can find it in are +3, +2, +1, 0, -1, -2, and -3 units of angular momentum (where the sign indicates the direction-- +3 is up, -3 is down).*****

Spin angular momentum has the same basic property-- it moves from some negative value to some positive value in steps of one unit of Planck's constant-- but with an important difference: the allowed states have *half*-integer values of angular momentum. For an electron, the maximum possible spin is 1/2 Planck's constant, so there are only two allowed states, +1/2 and -1/2. Since the sign indicates the direction, we tend to call these "spin-up" and "spin-down." *****

The first weird thing to jump out about this is that zero is not included. You can make a state that has zero spin angular momentum on average by adding together equal parts of spin-up and spin-down, but if you take one such system and ask "what is the angular momentum?" you will always get either +1/2 or -1/2, no matter what. There is no single measurement you can do on an electron spin that will ever give you an answer of zero. You might get an average value of zero after many measurements, but each individual measurement will give you either spin-up or spin-down.

This is a very strange idea, and very much unlike a classical system, or even quantized ordinary angular momentum. With an system having whole integer values of angular momentum, zero is always an option-- if you think of it like a record player, you can imagine it as having settings for 33 1/3 rpm, 45 rpm, both forward and reverse, but the turntable also has a power button-- you can always turn it off, and have angular momentum of zero. Electron spin is like a turntable with only forward and backward settings at a single speed, with the power cord wired directly into the mains so it can't be shut off. It's always spinning in one direction or the other.

That's not the weirdest part, though. The weird part comes when you look at what happens when you flip the spin twice. In a classical system, or a system of ordinary quantized angular momentum, when you rotate the direction of angular momentum through 360 degrees, you get back to where you started. If you start out in a state with one unit of angular momentum, then do something to move it from +1 to 0, then 0 to -1, then -1 to 0, and finally 0 back to +1, at the end of all that state-shifting, you end up with a state that is indistinguishable from an identical system that just sat in +1 the whole time.

When you do this with half-integer spin-- that is, take an electron in spin-up, flip it to spin-down, and then back to spin-up, you pick up a factor of -1. That is, the spin is pointing in the same direction it was at the start, but the overall wavefunction for that electron is multiplied by -1.

This is where the cute-toddler video comes in. If we imagine SteelyKid as a spinning electron, the climb-and-flip game in the video is like the rotation of an electron spin. At the start of the game, she's in a spin-up state (that is, standing upright):

Halfway through the game, she's in a spin-down state (upside down):

And at the end of the game, she's coming back to spin-up:

If you look closely at the first and last pictures, though, you can see that her state isn't identical-- in the final picture, her arms are twisted around (I picked a frame where she's not quite back to vertical so this would be clearer). She's made a 360 degree rotation of her body, but her overall state is different than it was at the start.

Of course, this analogy isn't perfect-- if you rotate a spin by 360 degrees, and then by 360 degrees again (in the same direction), you get back to exactly the state you started with. If I had SteelyKid do two consecutive climb-and-flips without letting her shift her grip in between, we'd end up in the emergency room with her shoulders dislocated, and Kate would divorce me.

To get a more complete analogy, all you need is a coffee cup, or other handled container. Hold the cup in your right hand, with the handle facing away from you. You can rotate the handle so that it faces you by curling your right arm toward yourself, and if you continue that motion, you can bring the handle back to pointing away from you, but your arm will be twisted into a slightly awkward position. If you continue the rotation through another 360 degrees, thought, you get back to the original situation, with your cup held comfortably pointing away from you.

That's a more complete analogy, but nowhere near as cute. Coffee cups don't giggle, or narrate their rotation. ("I'm climbing up!")

This strange rotation property is characteristic of half-integer spin angular momentum, and is one of the strangest properties of quantum physics. It's also one of the most important properties.

What does it mean for the electron wavefunction to be multiplied by -1? Not much, if you only have a single electron. Multiplying the overall wavefunction by -1 is the same as shifting the phase of a wave by 180 degrees, which does not by itself produce any interesting effects. A light wave that is delayed by half a wavelength before reaching you looks just the same as one with no delay, and an electron spin with a factor of -1 in front of the wavefunction behaves just the same as one where the wavefunction is multiplied by +1. (Note that the factor of -1 is on the wavefunction, not the spin-- it reflects a change in the external context, not a change from +1/2 to -1/2. In the video, the factor of -1 refers to the state of SteelyKid's arms, while the spin-up/spin-down information refers to the orientation of her body.)

This factor is critically important, though, when you talk about comparing spins to each other. In the same way that delaying a beam of light by half a wavelength has no effect on the intensity of that single beam, but takes you from constructive to destructive interference when you add it to a second beam of light, the effects of spin rotation have dramatic consequences when you are dealing with two or more electrons. In particular, this behavior under rotation is related to the Pauli exclusion principle that students of chemistry know and love.

Pauli exclusion says, in the form that we usually talk about, that no two spin-1/2 particles can ever be found in exactly the same state. This is a result of a deeper requirement, which says that the state of a collection of identical spin-1/2 particles can't depend on labelling individual particles-- if you switch the positions of electron 1 and electron 2, the physics has to be the same, up to an overall factor of +1 or -1 in front of the wavefunction.

Switching the state of two particles, though, is mathematically related to rotating the two spins by 360 degrees. And as we just saw, when you rotate a spin-1/2 particle by 360 degrees, it picks up a factor of -1. Thus, when you are dealing with spin-1/2 particles, swapping any two of them has to give you the same wavefunction you started with, multiplied by -1. When you work out the consequences of this, that means that there is no way for two spin-1/2 particles to be in exactly the same state at the same time (I talked about how to understand this a couple of years ago, copying an explanation from Feynman).

This also gives you features like the cancellation described in the topological insulator post, where there's an interference between the part of an electron's wavefunction that sees its spin rotate clockwise by 180 degrees, and the part that sees its spin rotate counter-clockwise by 180 degrees. If you think about it a little, you can see that getting from one of those states to the other involves a 360 degree rotation, which means that one is just a factor of -1 from the other. When you add those two pieces of the wavefunction together, then, they exactly cancel, which is why the surface states in topological insulators are insensitive to impurities, which is a big part of why they're considered so cool.

So, that's what you need to know about electron spin. To summarize, in bullet-point form:

- Electrons are not literally spinning balls of charge, but they do have intrinsic angular momentum.
- Spin angular momentum is real angular momentum.
- The angular momentum of a spin-1/2 particle like an electron is never zero.
- Rotating the spin of a spin-1/2 particle by 360 degrees doesn't get you exactly the state you started with, in the same way that the climb-and-flip game doesn't get your toddler back exactly the state she started in.
- This spin rotation property is one of the weirdest but most important features of the quantum theory of fundamental particles.
- SteelyKid is the cutest toddler in the universe.

OK, strictly speaking, that last one isn't about electrons. But it's true, and important. As additional proof, and as a reward for reading all the way to the end (you *did* read all the way to the end, didn't you?), here's the more advanced version of the climb-and-flip game, developed a little later that evening.

She's the cutest electron-analogue ever.

(***** As pointed out in comments, I'm glossing over one aspect of this-- the quantum states I mention in this post are the angular momentum along some axis in space. The choice of axis is arbitrary-- "up" and "down" are names given as a matter of convention, and "parallel" and "antiparallel" might be more appropriate. Once you've made your choice of axis, you will only ever measure the angular momentum to be one of a limited number of possible values, as described in the text.)

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Probably should mention the coffee cup should be empty!

Seriously though this was a great post. Very interesting and your daughter is too cute! Thanks for taking the time to post the things that you do. They help me a lot and I know I am not the only one.

I don't think you should say that the electron 'has only two possible states, "spin up" and "spin down."'

I'm pretty sure I've made something like the following comment before: what I think you should say is something like Measurements of the spin of an electron, in some direction v, have only two results, spin parallel to v or spin anti-parallel to v. Feel free to simplify the language.

The quantum state of the electron (not entering into the joys of quantum fields, whether relativistic or not) is a 2-dimensional complex vector (which is not restricted to only +/-1), which encodes with what probability we would obtain spin parallel or anti-parallel to v, whatever direction we choose for v. At least at this elementary level, a quantum state encodes probabilities of discrete events.

I recall that your response last time was that this is too much for the level you were aiming at, for dogs, but I take it that this distinction is fundamental enough that it should be made at the level of this post. At least you might avoid using the word "state" for a measurement outcome. Perhaps we'll agree to disagree again, but hey, you've said your piece again, so I have too.

Your turntable discussion lends itself to something, perhaps? "For a classical object, this angular momentum can point in absolutely any direction, and can be moved around by exerting forces in the appropriate places." In such cases, we discuss components of the measured angular momentum in a chosen direction. For an electron, a "quantum object", by contrast, when we measure angular momentum in any chosen direction we always obtain +1 or -1 (in units of hbar), but if we measure the angular momentum of lots of electrons, one by one, we obtain these results in different proportions depending on which direction we choose. Just as the three components of classical angular momentum in orthogonal directions allow us to predict what angular momentum we would measure in any direction, by taking an inner product, so the two complex components of the electron state allow us to predict the probabilities of obtaining +1 or -1 in any direction, by taking an inner product. I don't have as good a sense as you of what parts of this are not an elementary level.

Steelykid does the cute very well, but can you do a spin demo with Emmy?

I've never understood why Chem texts state that there are four quantum numbers. It seems one is missing.

n is the principal qn

the electron has angular momentum because it is moving

the magnitude of this is given by l and the direction is given by ml

also the electron is spinning

the magnitude of this is given by s and the direction is given by ms

I know the value for s (the spin qn, ms is the magnetic spin qn)) is 1/2 for all electrons and so it is typically ignored, but ignoring it leaves you spin angular momentum with direction but no magnitude.

Five quantum numbers.

I fully intended to specify that the angular momentum is measured relative to some arbitrary choice of axis when I was writing this, but somehow, it never made it into the text. I've added a footnote to the post to (hopefully) correct that.

The use of "state" for the result of a measurement outcome is a little cavalier, I suppose, but given that measurements in quantum systems are projective, and the system after measurement is left in the particular eigenstate whose eigenvalue was obtained as the measurement result, I don't think it's a big deal.

I've never understood why Chem texts state that there are four quantum numbers. It seems one is missing.

I think this is because, for most chemistry-related purposes, the difference in energy arising from a spin flip is completely negligible. There may be chemical situations in which the hyperfine splitting between two states is significant, but I bet there aren't many. The spin-orbit coupling may be more significant, but even that is pretty small.

I could be misrepresenting the field of chemistry, though-- my experience with quantum chem is limited to high school chemistry and one molecular spectroscopy course in grad school.

I know the value for s (the spin qn, ms is the magnetic spin qn)) is 1/2 for all electrons and so it is typically ignored

You answered your own question here. Every electron has the same magnitude of spin, so specifying that number doesn't tell you anything you didn't already know. The other four numbers are significant because they can (and must, since electrons are fermions) be different for each electron in a given atom. It matters whether you are talking about a 1s electron or a 4f electron, and the m_l and m_s numbers become important when you start dealing with Zeeman or Stark effects.

Now I realize why I always had trouble with the point charge spinning concept: Both my kids never went to the spin, the always insisted on inverting and being pulled back up!

My reply to @3 would be that the spin s isn't ignored, it's simply irrelevant because it can't change. Why bother writing something down when everyone knows what it is?

BTW, my apologies for ancient neurons firing but isn't there an F quantum number when the nuclear angular momentum gets involved in constructing atomic states, so LSJ is not enough?

BTW, my apologies for ancient neurons firing but isn't there an F quantum number when the nuclear angular momentum gets involved in constructing atomic states, so LSJ is not enough?

Yes. You pick up two more quantum numbers that way, so the full state is described by:

n- principal quantum number

L- orbital angular momentum

mL- orbital projection

S- spin angular momentum

mS- spin projection

J- spin+ orbital angular momentum

mJ- spin+orbital projection

I- Nuclear spin angular momentum

F- spin+orbital+nuclear spin angular momentum

mF- spin+orbital+nuclear spin projection

The F and mF states are often referred to as "hyperfine" quantum numbers, because that's the meaningful physical situation for which they're invoked.

Not really.

There's (supposedly) a Balinese water-pot dance that employs deal about two full rotations being needed to get back to the start: Hold the pot underneath, twist your arm through 360 deg, then lift your arm and carry the pot over your head in the same direction as the original twist, and then you can take your arm down twist-free.

A neat coincidence. I was just reading Tomonaga's "The Story of Spin" - his lectures from 1974. He goes over L.H. Thomas's analysis and how it affected Pauli's view, since Goudsmit, Uhlenbeck and Kronig missed the non-inertial aspect of what it looks like in the lab frame. Tomonaga makes it perfectly clear that sometimes physics is like pulling teeth !

The Electronâs puzzles

1900, 1905

Planck and Einstein found the energy of electron: E=h*f.

1916

Sommerfeld found the formula of electron : e^2=ah*c,

it means: e = +ah*c and e = -ah*c.

1928

Dirac found two more formulas of electronâs energy:

+E=Mc^2 and -E=Mc^2.

Questions.

Why does electron have five ( 5 ) formulas ?

Why does electron obey four ( 4) Laws ?

a) The Law of conservation and transformation energy/ mass

b) The Heisenberg Uncertainty Principle / Law

c) The Pauli Exclusion Principle/ Law

d) The Fermi-Dirac statistics

#

Diracâs formula E= (+ / -) E=Mc^2

on the one hand is a ârest particle, but on the other hand the

ârest particleâ haves enough active energy to blow up big cities

like Hiroshima and Nagasaki

My question is: Why can electronâs a rest/ potential energy

change into a high active energy?

Which electronâs act makes this process possible?

#

What is an electron ?

Now nobody knows

In the internet we can read hundreds theories of electron

All of them are problematical

We can read hundreds books and magazines about philosophy of physics

But how can we trust them if we donât have the real model of Electron ?

Best wishes.

Israel Sadovnik Socratus

Thx. Now I know how Buddhist monks fly magically through space-time :)